Dichloridodi-μ(2)-hydroxido-di-μ(3)-oxido-octa­phenyl­tetra­tin(IV) dimethyl sulfoxide disolvate

In the centrosymmetric tetra­nuclear title mol­ecule, [Sn(4)(C(6)H(5))(8)Cl(2)O(2)(OH)(2)]·2C(2)H(6)OS, the two independent tin(IV) atoms show distorted trigonal–bipyramidal SnC(2)O(3) and SnC(2)O(2)Cl coordination geometries. The four tin(IV) atoms are bridged by the hydroxo and oxo ligands, formin...

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Autores principales: Foladi, Shahrbano, Khazaei, Parivash, Attar Gharamaleki, Jafar, Notash, Behrouz, Rofouei, Mohammad Kazem
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569190/
https://www.ncbi.nlm.nih.gov/pubmed/23424434
http://dx.doi.org/10.1107/S1600536812051744
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author Foladi, Shahrbano
Khazaei, Parivash
Attar Gharamaleki, Jafar
Notash, Behrouz
Rofouei, Mohammad Kazem
author_facet Foladi, Shahrbano
Khazaei, Parivash
Attar Gharamaleki, Jafar
Notash, Behrouz
Rofouei, Mohammad Kazem
author_sort Foladi, Shahrbano
collection PubMed
description In the centrosymmetric tetra­nuclear title mol­ecule, [Sn(4)(C(6)H(5))(8)Cl(2)O(2)(OH)(2)]·2C(2)H(6)OS, the two independent tin(IV) atoms show distorted trigonal–bipyramidal SnC(2)O(3) and SnC(2)O(2)Cl coordination geometries. The four tin(IV) atoms are bridged by the hydroxo and oxo ligands, forming a ladder-like array of three edge-connected Sn(2)O(2) squares. The solvent mol­ecules are linked to the tetra­nuclear mol­ecule via O–H⋯O hydrogen bonds.
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spelling pubmed-35691902013-02-19 Dichloridodi-μ(2)-hydroxido-di-μ(3)-oxido-octa­phenyl­tetra­tin(IV) dimethyl sulfoxide disolvate Foladi, Shahrbano Khazaei, Parivash Attar Gharamaleki, Jafar Notash, Behrouz Rofouei, Mohammad Kazem Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric tetra­nuclear title mol­ecule, [Sn(4)(C(6)H(5))(8)Cl(2)O(2)(OH)(2)]·2C(2)H(6)OS, the two independent tin(IV) atoms show distorted trigonal–bipyramidal SnC(2)O(3) and SnC(2)O(2)Cl coordination geometries. The four tin(IV) atoms are bridged by the hydroxo and oxo ligands, forming a ladder-like array of three edge-connected Sn(2)O(2) squares. The solvent mol­ecules are linked to the tetra­nuclear mol­ecule via O–H⋯O hydrogen bonds. International Union of Crystallography 2013-01-09 /pmc/articles/PMC3569190/ /pubmed/23424434 http://dx.doi.org/10.1107/S1600536812051744 Text en © Foladi et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Foladi, Shahrbano
Khazaei, Parivash
Attar Gharamaleki, Jafar
Notash, Behrouz
Rofouei, Mohammad Kazem
Dichloridodi-μ(2)-hydroxido-di-μ(3)-oxido-octa­phenyl­tetra­tin(IV) dimethyl sulfoxide disolvate
title Dichloridodi-μ(2)-hydroxido-di-μ(3)-oxido-octa­phenyl­tetra­tin(IV) dimethyl sulfoxide disolvate
title_full Dichloridodi-μ(2)-hydroxido-di-μ(3)-oxido-octa­phenyl­tetra­tin(IV) dimethyl sulfoxide disolvate
title_fullStr Dichloridodi-μ(2)-hydroxido-di-μ(3)-oxido-octa­phenyl­tetra­tin(IV) dimethyl sulfoxide disolvate
title_full_unstemmed Dichloridodi-μ(2)-hydroxido-di-μ(3)-oxido-octa­phenyl­tetra­tin(IV) dimethyl sulfoxide disolvate
title_short Dichloridodi-μ(2)-hydroxido-di-μ(3)-oxido-octa­phenyl­tetra­tin(IV) dimethyl sulfoxide disolvate
title_sort dichloridodi-μ(2)-hydroxido-di-μ(3)-oxido-octa­phenyl­tetra­tin(iv) dimethyl sulfoxide disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569190/
https://www.ncbi.nlm.nih.gov/pubmed/23424434
http://dx.doi.org/10.1107/S1600536812051744
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