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rac-Dichlorido[3-eth­oxy-3-(1-ethyl-1H-benzimidazol-2-yl)-2,3-dihydro-1H-pyrrolo­[1,2-a]benzimidazole]­copper(II)

The title complex, [CuCl(2)(C(21)H(22)N(4)O)], contains a bis­(benzimidazole) unit with a chiral bridgehead C atom that forms part of a tetra­hydro­pyrrole ring fused to one of the benzimidazoles. The chelate angle is 90.45 (9)° and the dihedral angle between the essentially planar benzimidazole fra...

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Detalles Bibliográficos
Autores principales: Stibrany, Robert T., Potenza, Joseph A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569191/
https://www.ncbi.nlm.nih.gov/pubmed/23424435
http://dx.doi.org/10.1107/S1600536812051641
Descripción
Sumario:The title complex, [CuCl(2)(C(21)H(22)N(4)O)], contains a bis­(benzimidazole) unit with a chiral bridgehead C atom that forms part of a tetra­hydro­pyrrole ring fused to one of the benzimidazoles. The chelate angle is 90.45 (9)° and the dihedral angle between the essentially planar benzimidazole fragments is 26.68 (9)°. The Cu(II) coordination geometry lies approximately midway between tetra­hedral and square planar. Overall, each chiral mol­ecule contains six fused rings, and a racemic mixture is formed with symmetry-related enanti­omers. In the crystal, C—H⋯π and C—H⋯Cl inter­actions link mol­ecules into a supra­molecular chain along the a-axis direction.