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rac-Dichlorido[3-eth­oxy-3-(1-ethyl-1H-benzimidazol-2-yl)-2,3-dihydro-1H-pyrrolo­[1,2-a]benzimidazole]­copper(II)

The title complex, [CuCl(2)(C(21)H(22)N(4)O)], contains a bis­(benzimidazole) unit with a chiral bridgehead C atom that forms part of a tetra­hydro­pyrrole ring fused to one of the benzimidazoles. The chelate angle is 90.45 (9)° and the dihedral angle between the essentially planar benzimidazole fra...

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Detalles Bibliográficos
Autores principales: Stibrany, Robert T., Potenza, Joseph A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569191/
https://www.ncbi.nlm.nih.gov/pubmed/23424435
http://dx.doi.org/10.1107/S1600536812051641
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author Stibrany, Robert T.
Potenza, Joseph A.
author_facet Stibrany, Robert T.
Potenza, Joseph A.
author_sort Stibrany, Robert T.
collection PubMed
description The title complex, [CuCl(2)(C(21)H(22)N(4)O)], contains a bis­(benzimidazole) unit with a chiral bridgehead C atom that forms part of a tetra­hydro­pyrrole ring fused to one of the benzimidazoles. The chelate angle is 90.45 (9)° and the dihedral angle between the essentially planar benzimidazole fragments is 26.68 (9)°. The Cu(II) coordination geometry lies approximately midway between tetra­hedral and square planar. Overall, each chiral mol­ecule contains six fused rings, and a racemic mixture is formed with symmetry-related enanti­omers. In the crystal, C—H⋯π and C—H⋯Cl inter­actions link mol­ecules into a supra­molecular chain along the a-axis direction.
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spelling pubmed-35691912013-02-19 rac-Dichlorido[3-eth­oxy-3-(1-ethyl-1H-benzimidazol-2-yl)-2,3-dihydro-1H-pyrrolo­[1,2-a]benzimidazole]­copper(II) Stibrany, Robert T. Potenza, Joseph A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [CuCl(2)(C(21)H(22)N(4)O)], contains a bis­(benzimidazole) unit with a chiral bridgehead C atom that forms part of a tetra­hydro­pyrrole ring fused to one of the benzimidazoles. The chelate angle is 90.45 (9)° and the dihedral angle between the essentially planar benzimidazole fragments is 26.68 (9)°. The Cu(II) coordination geometry lies approximately midway between tetra­hedral and square planar. Overall, each chiral mol­ecule contains six fused rings, and a racemic mixture is formed with symmetry-related enanti­omers. In the crystal, C—H⋯π and C—H⋯Cl inter­actions link mol­ecules into a supra­molecular chain along the a-axis direction. International Union of Crystallography 2013-01-09 /pmc/articles/PMC3569191/ /pubmed/23424435 http://dx.doi.org/10.1107/S1600536812051641 Text en © Stibrany and Potenza 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Stibrany, Robert T.
Potenza, Joseph A.
rac-Dichlorido[3-eth­oxy-3-(1-ethyl-1H-benzimidazol-2-yl)-2,3-dihydro-1H-pyrrolo­[1,2-a]benzimidazole]­copper(II)
title rac-Dichlorido[3-eth­oxy-3-(1-ethyl-1H-benzimidazol-2-yl)-2,3-dihydro-1H-pyrrolo­[1,2-a]benzimidazole]­copper(II)
title_full rac-Dichlorido[3-eth­oxy-3-(1-ethyl-1H-benzimidazol-2-yl)-2,3-dihydro-1H-pyrrolo­[1,2-a]benzimidazole]­copper(II)
title_fullStr rac-Dichlorido[3-eth­oxy-3-(1-ethyl-1H-benzimidazol-2-yl)-2,3-dihydro-1H-pyrrolo­[1,2-a]benzimidazole]­copper(II)
title_full_unstemmed rac-Dichlorido[3-eth­oxy-3-(1-ethyl-1H-benzimidazol-2-yl)-2,3-dihydro-1H-pyrrolo­[1,2-a]benzimidazole]­copper(II)
title_short rac-Dichlorido[3-eth­oxy-3-(1-ethyl-1H-benzimidazol-2-yl)-2,3-dihydro-1H-pyrrolo­[1,2-a]benzimidazole]­copper(II)
title_sort rac-dichlorido[3-eth­oxy-3-(1-ethyl-1h-benzimidazol-2-yl)-2,3-dihydro-1h-pyrrolo­[1,2-a]benzimidazole]­copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569191/
https://www.ncbi.nlm.nih.gov/pubmed/23424435
http://dx.doi.org/10.1107/S1600536812051641
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