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rac-Dichlorido[3-ethoxy-3-(1-ethyl-1H-benzimidazol-2-yl)-2,3-dihydro-1H-pyrrolo[1,2-a]benzimidazole]copper(II)
The title complex, [CuCl(2)(C(21)H(22)N(4)O)], contains a bis(benzimidazole) unit with a chiral bridgehead C atom that forms part of a tetrahydropyrrole ring fused to one of the benzimidazoles. The chelate angle is 90.45 (9)° and the dihedral angle between the essentially planar benzimidazole fra...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569191/ https://www.ncbi.nlm.nih.gov/pubmed/23424435 http://dx.doi.org/10.1107/S1600536812051641 |
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author | Stibrany, Robert T. Potenza, Joseph A. |
author_facet | Stibrany, Robert T. Potenza, Joseph A. |
author_sort | Stibrany, Robert T. |
collection | PubMed |
description | The title complex, [CuCl(2)(C(21)H(22)N(4)O)], contains a bis(benzimidazole) unit with a chiral bridgehead C atom that forms part of a tetrahydropyrrole ring fused to one of the benzimidazoles. The chelate angle is 90.45 (9)° and the dihedral angle between the essentially planar benzimidazole fragments is 26.68 (9)°. The Cu(II) coordination geometry lies approximately midway between tetrahedral and square planar. Overall, each chiral molecule contains six fused rings, and a racemic mixture is formed with symmetry-related enantiomers. In the crystal, C—H⋯π and C—H⋯Cl interactions link molecules into a supramolecular chain along the a-axis direction. |
format | Online Article Text |
id | pubmed-3569191 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35691912013-02-19 rac-Dichlorido[3-ethoxy-3-(1-ethyl-1H-benzimidazol-2-yl)-2,3-dihydro-1H-pyrrolo[1,2-a]benzimidazole]copper(II) Stibrany, Robert T. Potenza, Joseph A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [CuCl(2)(C(21)H(22)N(4)O)], contains a bis(benzimidazole) unit with a chiral bridgehead C atom that forms part of a tetrahydropyrrole ring fused to one of the benzimidazoles. The chelate angle is 90.45 (9)° and the dihedral angle between the essentially planar benzimidazole fragments is 26.68 (9)°. The Cu(II) coordination geometry lies approximately midway between tetrahedral and square planar. Overall, each chiral molecule contains six fused rings, and a racemic mixture is formed with symmetry-related enantiomers. In the crystal, C—H⋯π and C—H⋯Cl interactions link molecules into a supramolecular chain along the a-axis direction. International Union of Crystallography 2013-01-09 /pmc/articles/PMC3569191/ /pubmed/23424435 http://dx.doi.org/10.1107/S1600536812051641 Text en © Stibrany and Potenza 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Stibrany, Robert T. Potenza, Joseph A. rac-Dichlorido[3-ethoxy-3-(1-ethyl-1H-benzimidazol-2-yl)-2,3-dihydro-1H-pyrrolo[1,2-a]benzimidazole]copper(II) |
title |
rac-Dichlorido[3-ethoxy-3-(1-ethyl-1H-benzimidazol-2-yl)-2,3-dihydro-1H-pyrrolo[1,2-a]benzimidazole]copper(II) |
title_full |
rac-Dichlorido[3-ethoxy-3-(1-ethyl-1H-benzimidazol-2-yl)-2,3-dihydro-1H-pyrrolo[1,2-a]benzimidazole]copper(II) |
title_fullStr |
rac-Dichlorido[3-ethoxy-3-(1-ethyl-1H-benzimidazol-2-yl)-2,3-dihydro-1H-pyrrolo[1,2-a]benzimidazole]copper(II) |
title_full_unstemmed |
rac-Dichlorido[3-ethoxy-3-(1-ethyl-1H-benzimidazol-2-yl)-2,3-dihydro-1H-pyrrolo[1,2-a]benzimidazole]copper(II) |
title_short |
rac-Dichlorido[3-ethoxy-3-(1-ethyl-1H-benzimidazol-2-yl)-2,3-dihydro-1H-pyrrolo[1,2-a]benzimidazole]copper(II) |
title_sort | rac-dichlorido[3-ethoxy-3-(1-ethyl-1h-benzimidazol-2-yl)-2,3-dihydro-1h-pyrrolo[1,2-a]benzimidazole]copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569191/ https://www.ncbi.nlm.nih.gov/pubmed/23424435 http://dx.doi.org/10.1107/S1600536812051641 |
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