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Diaquabis(1H-imidazole-4-carboxylato-κ(2) N (3),O)cobalt(II)
The title compound, [Co(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], contains a Co(II) cation on a twofold rotation axis, exhibiting a distorted octahedral coordination geometry. The equatorial plane is formed by two N,O-bidentate 1H-imidazole-4-carboxylate ligands and the axial positions are occupied by wate...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569192/ https://www.ncbi.nlm.nih.gov/pubmed/23424436 http://dx.doi.org/10.1107/S1600536813000330 |
| Sumario: | The title compound, [Co(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], contains a Co(II) cation on a twofold rotation axis, exhibiting a distorted octahedral coordination geometry. The equatorial plane is formed by two N,O-bidentate 1H-imidazole-4-carboxylate ligands and the axial positions are occupied by water molecules. The crystal packing consists of a three-dimensional network stabilized by O—H⋯O and N—H⋯O hydrogen bonds, together with weak π–π interactions [centroid–centroid distance = 3.577 (2) Å] between the imidazole rings. |
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