Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O)cobalt(II)

The title compound, [Co(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], contains a Co(II) cation on a twofold rotation axis, exhibiting a distorted octa­hedral coordination geometry. The equatorial plane is formed by two N,O-bidentate 1H-imidazole-4-carboxyl­ate ligands and the axial positions are occupied by wate...

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Detalles Bibliográficos
Autores principales: Artetxe, Beñat, San Felices, Leire, Pache, Aroa, Reinoso, Santiago, Gutiérrez-Zorrilla, Juan M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569192/
https://www.ncbi.nlm.nih.gov/pubmed/23424436
http://dx.doi.org/10.1107/S1600536813000330
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author Artetxe, Beñat
San Felices, Leire
Pache, Aroa
Reinoso, Santiago
Gutiérrez-Zorrilla, Juan M.
author_facet Artetxe, Beñat
San Felices, Leire
Pache, Aroa
Reinoso, Santiago
Gutiérrez-Zorrilla, Juan M.
author_sort Artetxe, Beñat
collection PubMed
description The title compound, [Co(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], contains a Co(II) cation on a twofold rotation axis, exhibiting a distorted octa­hedral coordination geometry. The equatorial plane is formed by two N,O-bidentate 1H-imidazole-4-carboxyl­ate ligands and the axial positions are occupied by water mol­ecules. The crystal packing consists of a three-dimensional network stabilized by O—H⋯O and N—H⋯O hydrogen bonds, together with weak π–π inter­actions [centroid–centroid distance = 3.577 (2) Å] between the imidazole rings.
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spelling pubmed-35691922013-02-19 Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O)cobalt(II) Artetxe, Beñat San Felices, Leire Pache, Aroa Reinoso, Santiago Gutiérrez-Zorrilla, Juan M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], contains a Co(II) cation on a twofold rotation axis, exhibiting a distorted octa­hedral coordination geometry. The equatorial plane is formed by two N,O-bidentate 1H-imidazole-4-carboxyl­ate ligands and the axial positions are occupied by water mol­ecules. The crystal packing consists of a three-dimensional network stabilized by O—H⋯O and N—H⋯O hydrogen bonds, together with weak π–π inter­actions [centroid–centroid distance = 3.577 (2) Å] between the imidazole rings. International Union of Crystallography 2013-01-09 /pmc/articles/PMC3569192/ /pubmed/23424436 http://dx.doi.org/10.1107/S1600536813000330 Text en © Artetxe et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Artetxe, Beñat
San Felices, Leire
Pache, Aroa
Reinoso, Santiago
Gutiérrez-Zorrilla, Juan M.
Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O)cobalt(II)
title Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O)cobalt(II)
title_full Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O)cobalt(II)
title_fullStr Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O)cobalt(II)
title_full_unstemmed Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O)cobalt(II)
title_short Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O)cobalt(II)
title_sort diaqua­bis­(1h-imidazole-4-carboxyl­ato-κ(2) n (3),o)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569192/
https://www.ncbi.nlm.nih.gov/pubmed/23424436
http://dx.doi.org/10.1107/S1600536813000330
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