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Bis{2-[(2,4,6-trimethyl­phen­yl)imino­methyl]pyrrol-1-ido}palladium(II)

The title compound, [Pd(C(14)H(15)N(2))(2)], is a square-planar palladium complex composed of two deprotonated pyrrole-2-carbaldimine ligands coordinating a central Pd(II) atom. In the crystal, three crystallographically independent complex mol­ecules are observed, one of which is located in a gener...

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Detalles Bibliográficos
Autor principal: Imhof, Wolfgang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569194/
https://www.ncbi.nlm.nih.gov/pubmed/23424438
http://dx.doi.org/10.1107/S1600536813000573
Descripción
Sumario:The title compound, [Pd(C(14)H(15)N(2))(2)], is a square-planar palladium complex composed of two deprotonated pyrrole-2-carbaldimine ligands coordinating a central Pd(II) atom. In the crystal, three crystallographically independent complex mol­ecules are observed, one of which is located in a general position, whereas the Pd(II) atoms of the other mol­ecules are situated on crystallographic inversion centers. The aromatic substituents at the imine N atoms in the three mol­ecules show dihedral angles of 87.6 (7)/83.64 (7), 74.3 (7) and 88.3 (7)° with respect to the corresponding PdN(4) plane.