Bis{2-[(2,4,6-trimethyl­phen­yl)imino­methyl]pyrrol-1-ido}palladium(II)

The title compound, [Pd(C(14)H(15)N(2))(2)], is a square-planar palladium complex composed of two deprotonated pyrrole-2-carbaldimine ligands coordinating a central Pd(II) atom. In the crystal, three crystallographically independent complex mol­ecules are observed, one of which is located in a gener...

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Detalles Bibliográficos
Autor principal: Imhof, Wolfgang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569194/
https://www.ncbi.nlm.nih.gov/pubmed/23424438
http://dx.doi.org/10.1107/S1600536813000573
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author Imhof, Wolfgang
author_facet Imhof, Wolfgang
author_sort Imhof, Wolfgang
collection PubMed
description The title compound, [Pd(C(14)H(15)N(2))(2)], is a square-planar palladium complex composed of two deprotonated pyrrole-2-carbaldimine ligands coordinating a central Pd(II) atom. In the crystal, three crystallographically independent complex mol­ecules are observed, one of which is located in a general position, whereas the Pd(II) atoms of the other mol­ecules are situated on crystallographic inversion centers. The aromatic substituents at the imine N atoms in the three mol­ecules show dihedral angles of 87.6 (7)/83.64 (7), 74.3 (7) and 88.3 (7)° with respect to the corresponding PdN(4) plane.
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spelling pubmed-35691942013-02-19 Bis{2-[(2,4,6-trimethyl­phen­yl)imino­methyl]pyrrol-1-ido}palladium(II) Imhof, Wolfgang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Pd(C(14)H(15)N(2))(2)], is a square-planar palladium complex composed of two deprotonated pyrrole-2-carbaldimine ligands coordinating a central Pd(II) atom. In the crystal, three crystallographically independent complex mol­ecules are observed, one of which is located in a general position, whereas the Pd(II) atoms of the other mol­ecules are situated on crystallographic inversion centers. The aromatic substituents at the imine N atoms in the three mol­ecules show dihedral angles of 87.6 (7)/83.64 (7), 74.3 (7) and 88.3 (7)° with respect to the corresponding PdN(4) plane. International Union of Crystallography 2013-01-12 /pmc/articles/PMC3569194/ /pubmed/23424438 http://dx.doi.org/10.1107/S1600536813000573 Text en © Wolfgang Imhof 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Imhof, Wolfgang
Bis{2-[(2,4,6-trimethyl­phen­yl)imino­methyl]pyrrol-1-ido}palladium(II)
title Bis{2-[(2,4,6-trimethyl­phen­yl)imino­methyl]pyrrol-1-ido}palladium(II)
title_full Bis{2-[(2,4,6-trimethyl­phen­yl)imino­methyl]pyrrol-1-ido}palladium(II)
title_fullStr Bis{2-[(2,4,6-trimethyl­phen­yl)imino­methyl]pyrrol-1-ido}palladium(II)
title_full_unstemmed Bis{2-[(2,4,6-trimethyl­phen­yl)imino­methyl]pyrrol-1-ido}palladium(II)
title_short Bis{2-[(2,4,6-trimethyl­phen­yl)imino­methyl]pyrrol-1-ido}palladium(II)
title_sort bis{2-[(2,4,6-trimethyl­phen­yl)imino­methyl]pyrrol-1-ido}palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569194/
https://www.ncbi.nlm.nih.gov/pubmed/23424438
http://dx.doi.org/10.1107/S1600536813000573
work_keys_str_mv AT imhofwolfgang bis2246trimethylphenyliminomethylpyrrol1idopalladiumii

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