[μ-6,9-Bis(carboxylatomethyl)-3,12-bis(car­boxymethyl)-3,6,9,12-tetraaza­tetradecanedioato]bis­[aqua­cobalt(II)] tetra­hydrate

The binuclear title complex, [Co(2)(C(18)H(26)N(4)O(12))(H(2)O)(2)]·4H(2)O, lies about a centre of inversion, the Co(II) atom being coordinated in a distorted octa­hedral arrangement defined by one water mol­ecule and N(2)O(3) donors derived from one end of a 6,9-bis(carboxylatomethyl)-3,12-bis(car­...

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Detalles Bibliográficos
Autores principales: Qian, Qi-feng, Wu, Jin-hui, Qian, Jin-liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569195/
https://www.ncbi.nlm.nih.gov/pubmed/23424439
http://dx.doi.org/10.1107/S1600536813000196
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author Qian, Qi-feng
Wu, Jin-hui
Qian, Jin-liang
author_facet Qian, Qi-feng
Wu, Jin-hui
Qian, Jin-liang
author_sort Qian, Qi-feng
collection PubMed
description The binuclear title complex, [Co(2)(C(18)H(26)N(4)O(12))(H(2)O)(2)]·4H(2)O, lies about a centre of inversion, the Co(II) atom being coordinated in a distorted octa­hedral arrangement defined by one water mol­ecule and N(2)O(3) donors derived from one end of a 6,9-bis(carboxylatomethyl)-3,12-bis(car­boxy­methyl)-3,6,9,12-tetraaza­tetradecanedioate (H(2)TTHA(4−)) tetra­anion. In the crystal, numerous O—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network.
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spelling pubmed-35691952013-02-19 [μ-6,9-Bis(carboxylatomethyl)-3,12-bis(car­boxymethyl)-3,6,9,12-tetraaza­tetradecanedioato]bis­[aqua­cobalt(II)] tetra­hydrate Qian, Qi-feng Wu, Jin-hui Qian, Jin-liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The binuclear title complex, [Co(2)(C(18)H(26)N(4)O(12))(H(2)O)(2)]·4H(2)O, lies about a centre of inversion, the Co(II) atom being coordinated in a distorted octa­hedral arrangement defined by one water mol­ecule and N(2)O(3) donors derived from one end of a 6,9-bis(carboxylatomethyl)-3,12-bis(car­boxy­methyl)-3,6,9,12-tetraaza­tetradecanedioate (H(2)TTHA(4−)) tetra­anion. In the crystal, numerous O—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. International Union of Crystallography 2013-01-12 /pmc/articles/PMC3569195/ /pubmed/23424439 http://dx.doi.org/10.1107/S1600536813000196 Text en © Qian et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Qian, Qi-feng
Wu, Jin-hui
Qian, Jin-liang
[μ-6,9-Bis(carboxylatomethyl)-3,12-bis(car­boxymethyl)-3,6,9,12-tetraaza­tetradecanedioato]bis­[aqua­cobalt(II)] tetra­hydrate
title [μ-6,9-Bis(carboxylatomethyl)-3,12-bis(car­boxymethyl)-3,6,9,12-tetraaza­tetradecanedioato]bis­[aqua­cobalt(II)] tetra­hydrate
title_full [μ-6,9-Bis(carboxylatomethyl)-3,12-bis(car­boxymethyl)-3,6,9,12-tetraaza­tetradecanedioato]bis­[aqua­cobalt(II)] tetra­hydrate
title_fullStr [μ-6,9-Bis(carboxylatomethyl)-3,12-bis(car­boxymethyl)-3,6,9,12-tetraaza­tetradecanedioato]bis­[aqua­cobalt(II)] tetra­hydrate
title_full_unstemmed [μ-6,9-Bis(carboxylatomethyl)-3,12-bis(car­boxymethyl)-3,6,9,12-tetraaza­tetradecanedioato]bis­[aqua­cobalt(II)] tetra­hydrate
title_short [μ-6,9-Bis(carboxylatomethyl)-3,12-bis(car­boxymethyl)-3,6,9,12-tetraaza­tetradecanedioato]bis­[aqua­cobalt(II)] tetra­hydrate
title_sort [μ-6,9-bis(carboxylatomethyl)-3,12-bis(car­boxymethyl)-3,6,9,12-tetraaza­tetradecanedioato]bis­[aqua­cobalt(ii)] tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569195/
https://www.ncbi.nlm.nih.gov/pubmed/23424439
http://dx.doi.org/10.1107/S1600536813000196
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