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(4-Chloroacetanilido-κ(2) N,O)bis[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III)
In the neutral mononuclear iridium(III) title compound, [Ir(C(8)H(7)ClNO)(C(11)H(8)N)(2)], the Ir(III) atom adopts an octahedral geometry, and is coordinated by two 2-phenylpyridyl ligands and one anionic 4-chloroacetanilide ligand. The 2-phenylpyridyl ligands are arranged in a cis-C,C′ and cis-...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569196/ https://www.ncbi.nlm.nih.gov/pubmed/23424440 http://dx.doi.org/10.1107/S1600536813000433 |
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author | Sun, Lijun Zhang, Songlin Song, Qijun |
author_facet | Sun, Lijun Zhang, Songlin Song, Qijun |
author_sort | Sun, Lijun |
collection | PubMed |
description | In the neutral mononuclear iridium(III) title compound, [Ir(C(8)H(7)ClNO)(C(11)H(8)N)(2)], the Ir(III) atom adopts an octahedral geometry, and is coordinated by two 2-phenylpyridyl ligands and one anionic 4-chloroacetanilide ligand. The 2-phenylpyridyl ligands are arranged in a cis-C,C′ and cis-N,N′ fashion. Each 2-phenylpyridyl ligand forms a five-membered ring with the Ir(III) atom. The 2-phenylpyridyl planes are perpendicular to each other [dihedral angle = 89.9 (1)°]. The Ir—C and Ir—N bond lengths are comparable to those reported for related iridium(III) 2-phenylpyridyl complexes. The remaining two coordination sites are occupied by the amidate N and O atoms, which form a four-membered ring with the iridium atom (Ir—N—C—O). The amidate plane is nearly perpendicular to both 2-phenylpyridyl ligands [dihedral angles = 87.8 (2) and 88.3 (2)°]. |
format | Online Article Text |
id | pubmed-3569196 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35691962013-02-19 (4-Chloroacetanilido-κ(2) N,O)bis[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III) Sun, Lijun Zhang, Songlin Song, Qijun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the neutral mononuclear iridium(III) title compound, [Ir(C(8)H(7)ClNO)(C(11)H(8)N)(2)], the Ir(III) atom adopts an octahedral geometry, and is coordinated by two 2-phenylpyridyl ligands and one anionic 4-chloroacetanilide ligand. The 2-phenylpyridyl ligands are arranged in a cis-C,C′ and cis-N,N′ fashion. Each 2-phenylpyridyl ligand forms a five-membered ring with the Ir(III) atom. The 2-phenylpyridyl planes are perpendicular to each other [dihedral angle = 89.9 (1)°]. The Ir—C and Ir—N bond lengths are comparable to those reported for related iridium(III) 2-phenylpyridyl complexes. The remaining two coordination sites are occupied by the amidate N and O atoms, which form a four-membered ring with the iridium atom (Ir—N—C—O). The amidate plane is nearly perpendicular to both 2-phenylpyridyl ligands [dihedral angles = 87.8 (2) and 88.3 (2)°]. International Union of Crystallography 2013-01-12 /pmc/articles/PMC3569196/ /pubmed/23424440 http://dx.doi.org/10.1107/S1600536813000433 Text en © Sun et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Sun, Lijun Zhang, Songlin Song, Qijun (4-Chloroacetanilido-κ(2) N,O)bis[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III) |
title | (4-Chloroacetanilido-κ(2)
N,O)bis[2-(pyridin-2-yl)phenyl-κ(2)
C
(1),N]iridium(III) |
title_full | (4-Chloroacetanilido-κ(2)
N,O)bis[2-(pyridin-2-yl)phenyl-κ(2)
C
(1),N]iridium(III) |
title_fullStr | (4-Chloroacetanilido-κ(2)
N,O)bis[2-(pyridin-2-yl)phenyl-κ(2)
C
(1),N]iridium(III) |
title_full_unstemmed | (4-Chloroacetanilido-κ(2)
N,O)bis[2-(pyridin-2-yl)phenyl-κ(2)
C
(1),N]iridium(III) |
title_short | (4-Chloroacetanilido-κ(2)
N,O)bis[2-(pyridin-2-yl)phenyl-κ(2)
C
(1),N]iridium(III) |
title_sort | (4-chloroacetanilido-κ(2)
n,o)bis[2-(pyridin-2-yl)phenyl-κ(2)
c
(1),n]iridium(iii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569196/ https://www.ncbi.nlm.nih.gov/pubmed/23424440 http://dx.doi.org/10.1107/S1600536813000433 |
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