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(4-Chloro­acetanilido-κ(2) N,O)bis­[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III)

In the neutral mononuclear iridium(III) title compound, [Ir(C(8)H(7)ClNO)(C(11)H(8)N)(2)], the Ir(III) atom adopts an octa­hedral geometry, and is coordinated by two 2-phenyl­pyridyl ligands and one anionic 4-chloro­acetanilide ligand. The 2-phenyl­pyridyl ligands are arranged in a cis-C,C′ and cis-...

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Detalles Bibliográficos
Autores principales: Sun, Lijun, Zhang, Songlin, Song, Qijun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569196/
https://www.ncbi.nlm.nih.gov/pubmed/23424440
http://dx.doi.org/10.1107/S1600536813000433
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author Sun, Lijun
Zhang, Songlin
Song, Qijun
author_facet Sun, Lijun
Zhang, Songlin
Song, Qijun
author_sort Sun, Lijun
collection PubMed
description In the neutral mononuclear iridium(III) title compound, [Ir(C(8)H(7)ClNO)(C(11)H(8)N)(2)], the Ir(III) atom adopts an octa­hedral geometry, and is coordinated by two 2-phenyl­pyridyl ligands and one anionic 4-chloro­acetanilide ligand. The 2-phenyl­pyridyl ligands are arranged in a cis-C,C′ and cis-N,N′ fashion. Each 2-phenyl­pyridyl ligand forms a five-membered ring with the Ir(III) atom. The 2-phenyl­pyridyl planes are perpendicular to each other [dihedral angle = 89.9 (1)°]. The Ir—C and Ir—N bond lengths are comparable to those reported for related iridium(III) 2-phenyl­pyridyl complexes. The remaining two coordination sites are occupied by the amidate N and O atoms, which form a four-membered ring with the iridium atom (Ir—N—C—O). The amidate plane is nearly perpendicular to both 2-phenyl­pyridyl ligands [dihedral angles = 87.8 (2) and 88.3 (2)°].
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spelling pubmed-35691962013-02-19 (4-Chloro­acetanilido-κ(2) N,O)bis­[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III) Sun, Lijun Zhang, Songlin Song, Qijun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the neutral mononuclear iridium(III) title compound, [Ir(C(8)H(7)ClNO)(C(11)H(8)N)(2)], the Ir(III) atom adopts an octa­hedral geometry, and is coordinated by two 2-phenyl­pyridyl ligands and one anionic 4-chloro­acetanilide ligand. The 2-phenyl­pyridyl ligands are arranged in a cis-C,C′ and cis-N,N′ fashion. Each 2-phenyl­pyridyl ligand forms a five-membered ring with the Ir(III) atom. The 2-phenyl­pyridyl planes are perpendicular to each other [dihedral angle = 89.9 (1)°]. The Ir—C and Ir—N bond lengths are comparable to those reported for related iridium(III) 2-phenyl­pyridyl complexes. The remaining two coordination sites are occupied by the amidate N and O atoms, which form a four-membered ring with the iridium atom (Ir—N—C—O). The amidate plane is nearly perpendicular to both 2-phenyl­pyridyl ligands [dihedral angles = 87.8 (2) and 88.3 (2)°]. International Union of Crystallography 2013-01-12 /pmc/articles/PMC3569196/ /pubmed/23424440 http://dx.doi.org/10.1107/S1600536813000433 Text en © Sun et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sun, Lijun
Zhang, Songlin
Song, Qijun
(4-Chloro­acetanilido-κ(2) N,O)bis­[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III)
title (4-Chloro­acetanilido-κ(2) N,O)bis­[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III)
title_full (4-Chloro­acetanilido-κ(2) N,O)bis­[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III)
title_fullStr (4-Chloro­acetanilido-κ(2) N,O)bis­[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III)
title_full_unstemmed (4-Chloro­acetanilido-κ(2) N,O)bis­[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III)
title_short (4-Chloro­acetanilido-κ(2) N,O)bis­[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III)
title_sort (4-chloro­acetanilido-κ(2) n,o)bis­[2-(pyridin-2-yl)phenyl-κ(2) c (1),n]iridium(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569196/
https://www.ncbi.nlm.nih.gov/pubmed/23424440
http://dx.doi.org/10.1107/S1600536813000433
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