Bis[μ-4-(4-carb­oxy­phen­oxy)phthalato]bis­[triaqua­cobalt(II)]

The dinuclear title complex, [Co(2)(C(15)H(8)O(7))(2)(H(2)O)(6)], lies across an inversion center. The unique Co(II) ion is coordinated in a slightly distorted octa­hedral coordination geometry by two O atoms from a chelating 4-(carb­oxy­phen­oxy)phthalate ligand, three water O atoms and a further O...

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Detalles Bibliográficos
Autor principal: Wang, Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569198/
https://www.ncbi.nlm.nih.gov/pubmed/23424399
http://dx.doi.org/10.1107/S1600536813000536
Descripción
Sumario:The dinuclear title complex, [Co(2)(C(15)H(8)O(7))(2)(H(2)O)(6)], lies across an inversion center. The unique Co(II) ion is coordinated in a slightly distorted octa­hedral coordination geometry by two O atoms from a chelating 4-(carb­oxy­phen­oxy)phthalate ligand, three water O atoms and a further O atom from a bridging carboxyl­ate group of a symmetry-related 4-(carb­oxy­phen­oxy)phthalate ligand. In the crystal, O—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network.

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