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Bis[μ-4-(4-carboxyphenoxy)phthalato]bis[triaquacobalt(II)]
The dinuclear title complex, [Co(2)(C(15)H(8)O(7))(2)(H(2)O)(6)], lies across an inversion center. The unique Co(II) ion is coordinated in a slightly distorted octahedral coordination geometry by two O atoms from a chelating 4-(carboxyphenoxy)phthalate ligand, three water O atoms and a further O...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2013
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569198/ https://www.ncbi.nlm.nih.gov/pubmed/23424399 http://dx.doi.org/10.1107/S1600536813000536 |
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author | Wang, Liang |
author_facet | Wang, Liang |
author_sort | Wang, Liang |
collection | PubMed |
description | The dinuclear title complex, [Co(2)(C(15)H(8)O(7))(2)(H(2)O)(6)], lies across an inversion center. The unique Co(II) ion is coordinated in a slightly distorted octahedral coordination geometry by two O atoms from a chelating 4-(carboxyphenoxy)phthalate ligand, three water O atoms and a further O atom from a bridging carboxylate group of a symmetry-related 4-(carboxyphenoxy)phthalate ligand. In the crystal, O—H⋯O hydrogen bonds link the molecules into a three-dimensional network. |
format | Online Article Text |
id | pubmed-3569198 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35691982013-02-19 Bis[μ-4-(4-carboxyphenoxy)phthalato]bis[triaquacobalt(II)] Wang, Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dinuclear title complex, [Co(2)(C(15)H(8)O(7))(2)(H(2)O)(6)], lies across an inversion center. The unique Co(II) ion is coordinated in a slightly distorted octahedral coordination geometry by two O atoms from a chelating 4-(carboxyphenoxy)phthalate ligand, three water O atoms and a further O atom from a bridging carboxylate group of a symmetry-related 4-(carboxyphenoxy)phthalate ligand. In the crystal, O—H⋯O hydrogen bonds link the molecules into a three-dimensional network. International Union of Crystallography 2013-01-12 /pmc/articles/PMC3569198/ /pubmed/23424399 http://dx.doi.org/10.1107/S1600536813000536 Text en © Liang Wang 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Liang Bis[μ-4-(4-carboxyphenoxy)phthalato]bis[triaquacobalt(II)] |
title | Bis[μ-4-(4-carboxyphenoxy)phthalato]bis[triaquacobalt(II)] |
title_full | Bis[μ-4-(4-carboxyphenoxy)phthalato]bis[triaquacobalt(II)] |
title_fullStr | Bis[μ-4-(4-carboxyphenoxy)phthalato]bis[triaquacobalt(II)] |
title_full_unstemmed | Bis[μ-4-(4-carboxyphenoxy)phthalato]bis[triaquacobalt(II)] |
title_short | Bis[μ-4-(4-carboxyphenoxy)phthalato]bis[triaquacobalt(II)] |
title_sort | bis[μ-4-(4-carboxyphenoxy)phthalato]bis[triaquacobalt(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569198/ https://www.ncbi.nlm.nih.gov/pubmed/23424399 http://dx.doi.org/10.1107/S1600536813000536 |
work_keys_str_mv | AT wangliang bism44carboxyphenoxyphthalatobistriaquacobaltii |