catena-Poly[(acetato­chloridozinc)-μ-1,1′-[1,4-phenyl­enebis(methyl­ene)]di-1H-imidazole]

The title compound, [Zn(CH(3)CO(2))Cl(C(14)H(14)N(4))](n), is a one-dimensional coordination polymer in which the Zn(II) ion is tetrahedrally ­coordinated by two N atoms of a bridging 1,1′-[1,4-phenyl­enebis(methyl­ene)]di-1H-imidazole ligand, an acetate O atom and a Cl atom. The Cl atom, two acetat...

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Detalles Bibliográficos
Autor principal: Wang, Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569199/
https://www.ncbi.nlm.nih.gov/pubmed/23424400
http://dx.doi.org/10.1107/S1600536813000524
Descripción
Sumario:The title compound, [Zn(CH(3)CO(2))Cl(C(14)H(14)N(4))](n), is a one-dimensional coordination polymer in which the Zn(II) ion is tetrahedrally ­coordinated by two N atoms of a bridging 1,1′-[1,4-phenyl­enebis(methyl­ene)]di-1H-imidazole ligand, an acetate O atom and a Cl atom. The Cl atom, two acetate O atoms and two acetate C atoms are located on a mirror plane. The coordination of the diimidazole ligand to the Zn(II) ion gives an infinite one-dimensional zigzag structure along the b-axis direction with the charge balanced by the chloride and acetate ions.

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