Cargando…

Tetra­methyl­ammonium aqua­trichlorido­oxalatostannate(IV) monohydrate

The Sn(IV) atom in the title compound, [(CH(3))(4)N][Sn(C(2)O(4))Cl(3)(H(2)O)]·H(2)O, obtained from the reaction between SnCl(4) and [(CH(3))(4)N](2)C(2)O(4)·2H(2)O, is six-coordinated by three Cl atoms, an O atom of a water mol­ecule and two O atoms from an asymmetrically chelating oxalate anion. T...

Descripción completa

Detalles Bibliográficos
Autores principales: Sow, Yaya, Diop, Libasse, Molloy, Kieran C., Kociok-Köhn, Gabriele
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569201/
https://www.ncbi.nlm.nih.gov/pubmed/23424403
http://dx.doi.org/10.1107/S1600536813000895
_version_ 1782258850477375488
author Sow, Yaya
Diop, Libasse
Molloy, Kieran C.
Kociok-Köhn, Gabriele
author_facet Sow, Yaya
Diop, Libasse
Molloy, Kieran C.
Kociok-Köhn, Gabriele
author_sort Sow, Yaya
collection PubMed
description The Sn(IV) atom in the title compound, [(CH(3))(4)N][Sn(C(2)O(4))Cl(3)(H(2)O)]·H(2)O, obtained from the reaction between SnCl(4) and [(CH(3))(4)N](2)C(2)O(4)·2H(2)O, is six-coordinated by three Cl atoms, an O atom of a water mol­ecule and two O atoms from an asymmetrically chelating oxalate anion. The environment around the Sn(IV) atom is distorted octa­hedral. The anions are connected by the lattice water mol­ecule through O—H⋯O hydrogen bonds, leading to a layered structure parallel to (010). The cations are located between these layers and besides Coulombic forces are connected to the anionic layers through weak C—H⋯O and C—H⋯Cl inter­actions.
format Online
Article
Text
id pubmed-3569201
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-35692012013-02-19 Tetra­methyl­ammonium aqua­trichlorido­oxalatostannate(IV) monohydrate Sow, Yaya Diop, Libasse Molloy, Kieran C. Kociok-Köhn, Gabriele Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn(IV) atom in the title compound, [(CH(3))(4)N][Sn(C(2)O(4))Cl(3)(H(2)O)]·H(2)O, obtained from the reaction between SnCl(4) and [(CH(3))(4)N](2)C(2)O(4)·2H(2)O, is six-coordinated by three Cl atoms, an O atom of a water mol­ecule and two O atoms from an asymmetrically chelating oxalate anion. The environment around the Sn(IV) atom is distorted octa­hedral. The anions are connected by the lattice water mol­ecule through O—H⋯O hydrogen bonds, leading to a layered structure parallel to (010). The cations are located between these layers and besides Coulombic forces are connected to the anionic layers through weak C—H⋯O and C—H⋯Cl inter­actions. International Union of Crystallography 2013-01-16 /pmc/articles/PMC3569201/ /pubmed/23424403 http://dx.doi.org/10.1107/S1600536813000895 Text en © Sow et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sow, Yaya
Diop, Libasse
Molloy, Kieran C.
Kociok-Köhn, Gabriele
Tetra­methyl­ammonium aqua­trichlorido­oxalatostannate(IV) monohydrate
title Tetra­methyl­ammonium aqua­trichlorido­oxalatostannate(IV) monohydrate
title_full Tetra­methyl­ammonium aqua­trichlorido­oxalatostannate(IV) monohydrate
title_fullStr Tetra­methyl­ammonium aqua­trichlorido­oxalatostannate(IV) monohydrate
title_full_unstemmed Tetra­methyl­ammonium aqua­trichlorido­oxalatostannate(IV) monohydrate
title_short Tetra­methyl­ammonium aqua­trichlorido­oxalatostannate(IV) monohydrate
title_sort tetra­methyl­ammonium aqua­trichlorido­oxalatostannate(iv) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569201/
https://www.ncbi.nlm.nih.gov/pubmed/23424403
http://dx.doi.org/10.1107/S1600536813000895
work_keys_str_mv AT sowyaya tetramethylammoniumaquatrichloridooxalatostannateivmonohydrate
AT dioplibasse tetramethylammoniumaquatrichloridooxalatostannateivmonohydrate
AT molloykieranc tetramethylammoniumaquatrichloridooxalatostannateivmonohydrate
AT kociokkohngabriele tetramethylammoniumaquatrichloridooxalatostannateivmonohydrate