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Tetramethylammonium aquatrichloridooxalatostannate(IV) monohydrate
The Sn(IV) atom in the title compound, [(CH(3))(4)N][Sn(C(2)O(4))Cl(3)(H(2)O)]·H(2)O, obtained from the reaction between SnCl(4) and [(CH(3))(4)N](2)C(2)O(4)·2H(2)O, is six-coordinated by three Cl atoms, an O atom of a water molecule and two O atoms from an asymmetrically chelating oxalate anion. T...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569201/ https://www.ncbi.nlm.nih.gov/pubmed/23424403 http://dx.doi.org/10.1107/S1600536813000895 |
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author | Sow, Yaya Diop, Libasse Molloy, Kieran C. Kociok-Köhn, Gabriele |
author_facet | Sow, Yaya Diop, Libasse Molloy, Kieran C. Kociok-Köhn, Gabriele |
author_sort | Sow, Yaya |
collection | PubMed |
description | The Sn(IV) atom in the title compound, [(CH(3))(4)N][Sn(C(2)O(4))Cl(3)(H(2)O)]·H(2)O, obtained from the reaction between SnCl(4) and [(CH(3))(4)N](2)C(2)O(4)·2H(2)O, is six-coordinated by three Cl atoms, an O atom of a water molecule and two O atoms from an asymmetrically chelating oxalate anion. The environment around the Sn(IV) atom is distorted octahedral. The anions are connected by the lattice water molecule through O—H⋯O hydrogen bonds, leading to a layered structure parallel to (010). The cations are located between these layers and besides Coulombic forces are connected to the anionic layers through weak C—H⋯O and C—H⋯Cl interactions. |
format | Online Article Text |
id | pubmed-3569201 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35692012013-02-19 Tetramethylammonium aquatrichloridooxalatostannate(IV) monohydrate Sow, Yaya Diop, Libasse Molloy, Kieran C. Kociok-Köhn, Gabriele Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn(IV) atom in the title compound, [(CH(3))(4)N][Sn(C(2)O(4))Cl(3)(H(2)O)]·H(2)O, obtained from the reaction between SnCl(4) and [(CH(3))(4)N](2)C(2)O(4)·2H(2)O, is six-coordinated by three Cl atoms, an O atom of a water molecule and two O atoms from an asymmetrically chelating oxalate anion. The environment around the Sn(IV) atom is distorted octahedral. The anions are connected by the lattice water molecule through O—H⋯O hydrogen bonds, leading to a layered structure parallel to (010). The cations are located between these layers and besides Coulombic forces are connected to the anionic layers through weak C—H⋯O and C—H⋯Cl interactions. International Union of Crystallography 2013-01-16 /pmc/articles/PMC3569201/ /pubmed/23424403 http://dx.doi.org/10.1107/S1600536813000895 Text en © Sow et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Sow, Yaya Diop, Libasse Molloy, Kieran C. Kociok-Köhn, Gabriele Tetramethylammonium aquatrichloridooxalatostannate(IV) monohydrate |
title | Tetramethylammonium aquatrichloridooxalatostannate(IV) monohydrate |
title_full | Tetramethylammonium aquatrichloridooxalatostannate(IV) monohydrate |
title_fullStr | Tetramethylammonium aquatrichloridooxalatostannate(IV) monohydrate |
title_full_unstemmed | Tetramethylammonium aquatrichloridooxalatostannate(IV) monohydrate |
title_short | Tetramethylammonium aquatrichloridooxalatostannate(IV) monohydrate |
title_sort | tetramethylammonium aquatrichloridooxalatostannate(iv) monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569201/ https://www.ncbi.nlm.nih.gov/pubmed/23424403 http://dx.doi.org/10.1107/S1600536813000895 |
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