Dichlorido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)mercury(II)

The title compound, [HgCl(2)(C(14)H(12)N(2))], consists of one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand chelating the Hg(II) ion and two chloride ligands coordinating to the Hg(II) ion, forming a distorted tetra­hedral environment. The dmphen ligand is nearly planar (r.m.s. deviation = 0.022...

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Detalles Bibliográficos
Autores principales: Warad, Ismail, Al-Noaimi, Mousa, Haddad, Salim F., Othman, Rema
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569203/
https://www.ncbi.nlm.nih.gov/pubmed/23424405
http://dx.doi.org/10.1107/S1600536813001086
Descripción
Sumario:The title compound, [HgCl(2)(C(14)H(12)N(2))], consists of one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand chelating the Hg(II) ion and two chloride ligands coordinating to the Hg(II) ion, forming a distorted tetra­hedral environment. The dmphen ligand is nearly planar (r.m.s. deviation = 0.0225 Å). The dihedral angle between the normal to the plane defined by the Hg(II) atom and the two Cl atoms and the normal to the plane of the dmphen ring is 81.8 (1)°.

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