Dichlorido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)mercury(II)

The title compound, [HgCl(2)(C(14)H(12)N(2))], consists of one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand chelating the Hg(II) ion and two chloride ligands coordinating to the Hg(II) ion, forming a distorted tetra­hedral environment. The dmphen ligand is nearly planar (r.m.s. deviation = 0.022...

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Detalles Bibliográficos
Autores principales: Warad, Ismail, Al-Noaimi, Mousa, Haddad, Salim F., Othman, Rema
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569203/
https://www.ncbi.nlm.nih.gov/pubmed/23424405
http://dx.doi.org/10.1107/S1600536813001086
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author Warad, Ismail
Al-Noaimi, Mousa
Haddad, Salim F.
Othman, Rema
author_facet Warad, Ismail
Al-Noaimi, Mousa
Haddad, Salim F.
Othman, Rema
author_sort Warad, Ismail
collection PubMed
description The title compound, [HgCl(2)(C(14)H(12)N(2))], consists of one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand chelating the Hg(II) ion and two chloride ligands coordinating to the Hg(II) ion, forming a distorted tetra­hedral environment. The dmphen ligand is nearly planar (r.m.s. deviation = 0.0225 Å). The dihedral angle between the normal to the plane defined by the Hg(II) atom and the two Cl atoms and the normal to the plane of the dmphen ring is 81.8 (1)°.
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spelling pubmed-35692032013-02-19 Dichlorido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)mercury(II) Warad, Ismail Al-Noaimi, Mousa Haddad, Salim F. Othman, Rema Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [HgCl(2)(C(14)H(12)N(2))], consists of one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand chelating the Hg(II) ion and two chloride ligands coordinating to the Hg(II) ion, forming a distorted tetra­hedral environment. The dmphen ligand is nearly planar (r.m.s. deviation = 0.0225 Å). The dihedral angle between the normal to the plane defined by the Hg(II) atom and the two Cl atoms and the normal to the plane of the dmphen ring is 81.8 (1)°. International Union of Crystallography 2013-01-19 /pmc/articles/PMC3569203/ /pubmed/23424405 http://dx.doi.org/10.1107/S1600536813001086 Text en © Warad et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Warad, Ismail
Al-Noaimi, Mousa
Haddad, Salim F.
Othman, Rema
Dichlorido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)mercury(II)
title Dichlorido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)mercury(II)
title_full Dichlorido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)mercury(II)
title_fullStr Dichlorido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)mercury(II)
title_full_unstemmed Dichlorido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)mercury(II)
title_short Dichlorido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)mercury(II)
title_sort dichlorido(2,9-dimethyl-1,10-phenanthroline-κ(2) n,n′)mercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569203/
https://www.ncbi.nlm.nih.gov/pubmed/23424405
http://dx.doi.org/10.1107/S1600536813001086
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