trans-Dibromidobis(3-methyl­pyridine-κN)copper(II)

The asymmetric unit of the title compound, [CuBr(2)(C(6)H(7)N)(2)], contains one half-mol­ecule, the whole mol­ecule being generated by inversion through a center located at the Cu(II) atom. The geometry around the Cu(II) atom is square planar. Semicoordinate Cu⋯Br bonds [3.269 (1) Å] and nonclassic...

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Detalles Bibliográficos
Autor principal: Awwadi, Firas F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569207/
https://www.ncbi.nlm.nih.gov/pubmed/23424409
http://dx.doi.org/10.1107/S1600536813001414
Descripción
Sumario:The asymmetric unit of the title compound, [CuBr(2)(C(6)H(7)N)(2)], contains one half-mol­ecule, the whole mol­ecule being generated by inversion through a center located at the Cu(II) atom. The geometry around the Cu(II) atom is square planar. Semicoordinate Cu⋯Br bonds [3.269 (1) Å] and nonclassical C—H⋯Br hydrogen bonds connect the mol­ecules, forming chains running parallel to the a axis. These chains are further linked via additional C—H⋯Br hydrogen bonds into a three-dimensional network.

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