trans-Dibromidobis(3-methyl­pyridine-κN)copper(II)

The asymmetric unit of the title compound, [CuBr(2)(C(6)H(7)N)(2)], contains one half-mol­ecule, the whole mol­ecule being generated by inversion through a center located at the Cu(II) atom. The geometry around the Cu(II) atom is square planar. Semicoordinate Cu⋯Br bonds [3.269 (1) Å] and nonclassic...

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Detalles Bibliográficos
Autor principal: Awwadi, Firas F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569207/
https://www.ncbi.nlm.nih.gov/pubmed/23424409
http://dx.doi.org/10.1107/S1600536813001414
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author Awwadi, Firas F.
author_facet Awwadi, Firas F.
author_sort Awwadi, Firas F.
collection PubMed
description The asymmetric unit of the title compound, [CuBr(2)(C(6)H(7)N)(2)], contains one half-mol­ecule, the whole mol­ecule being generated by inversion through a center located at the Cu(II) atom. The geometry around the Cu(II) atom is square planar. Semicoordinate Cu⋯Br bonds [3.269 (1) Å] and nonclassical C—H⋯Br hydrogen bonds connect the mol­ecules, forming chains running parallel to the a axis. These chains are further linked via additional C—H⋯Br hydrogen bonds into a three-dimensional network.
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spelling pubmed-35692072013-02-19 trans-Dibromidobis(3-methyl­pyridine-κN)copper(II) Awwadi, Firas F. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [CuBr(2)(C(6)H(7)N)(2)], contains one half-mol­ecule, the whole mol­ecule being generated by inversion through a center located at the Cu(II) atom. The geometry around the Cu(II) atom is square planar. Semicoordinate Cu⋯Br bonds [3.269 (1) Å] and nonclassical C—H⋯Br hydrogen bonds connect the mol­ecules, forming chains running parallel to the a axis. These chains are further linked via additional C—H⋯Br hydrogen bonds into a three-dimensional network. International Union of Crystallography 2013-01-19 /pmc/articles/PMC3569207/ /pubmed/23424409 http://dx.doi.org/10.1107/S1600536813001414 Text en © Firas F. Awwadi 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Awwadi, Firas F.
trans-Dibromidobis(3-methyl­pyridine-κN)copper(II)
title trans-Dibromidobis(3-methyl­pyridine-κN)copper(II)
title_full trans-Dibromidobis(3-methyl­pyridine-κN)copper(II)
title_fullStr trans-Dibromidobis(3-methyl­pyridine-κN)copper(II)
title_full_unstemmed trans-Dibromidobis(3-methyl­pyridine-κN)copper(II)
title_short trans-Dibromidobis(3-methyl­pyridine-κN)copper(II)
title_sort trans-dibromidobis(3-methyl­pyridine-κn)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569207/
https://www.ncbi.nlm.nih.gov/pubmed/23424409
http://dx.doi.org/10.1107/S1600536813001414
work_keys_str_mv AT awwadifirasf transdibromidobis3methylpyridinekncopperii

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