cis-Dichlorido(dimethyl sulfoxide-κS)(N,N,N′,N′-tetra­methyl­guanidine-κN′′)platinum(II)

In the title compound, cis-[PtCl(2)(C(5)H(13)N(3))(C(2)H(6)OS)], the four-coordinate Pt(II) atom is bonded to one N atom of the N,N,N′,N′-tetra­methyl­guanidine ligand, one dimethyl sulfoxide S atom and two chloride ligands, forming a cis-square-planar geometry. The bond lengths and angles of the N—...

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Autores principales: Eliseev, Ivan I., Bokach, Nadezhda A., Haukka, Matti, Golenya, Irina A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569208/
https://www.ncbi.nlm.nih.gov/pubmed/23424410
http://dx.doi.org/10.1107/S160053681300130X
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author Eliseev, Ivan I.
Bokach, Nadezhda A.
Haukka, Matti
Golenya, Irina A.
author_facet Eliseev, Ivan I.
Bokach, Nadezhda A.
Haukka, Matti
Golenya, Irina A.
author_sort Eliseev, Ivan I.
collection PubMed
description In the title compound, cis-[PtCl(2)(C(5)H(13)N(3))(C(2)H(6)OS)], the four-coordinate Pt(II) atom is bonded to one N atom of the N,N,N′,N′-tetra­methyl­guanidine ligand, one dimethyl sulfoxide S atom and two chloride ligands, forming a cis-square-planar geometry. The bond lengths and angles of the N—Pt—Cl functionality are typical for imine dichloridoplatinum(II) complexes. The H atom of the imino group is oriented towards the O atom of the sulfoxide group of a neighboring mol­ecule and forms an N—H⋯O hydrogen bond.
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spelling pubmed-35692082013-02-19 cis-Dichlorido(dimethyl sulfoxide-κS)(N,N,N′,N′-tetra­methyl­guanidine-κN′′)platinum(II) Eliseev, Ivan I. Bokach, Nadezhda A. Haukka, Matti Golenya, Irina A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, cis-[PtCl(2)(C(5)H(13)N(3))(C(2)H(6)OS)], the four-coordinate Pt(II) atom is bonded to one N atom of the N,N,N′,N′-tetra­methyl­guanidine ligand, one dimethyl sulfoxide S atom and two chloride ligands, forming a cis-square-planar geometry. The bond lengths and angles of the N—Pt—Cl functionality are typical for imine dichloridoplatinum(II) complexes. The H atom of the imino group is oriented towards the O atom of the sulfoxide group of a neighboring mol­ecule and forms an N—H⋯O hydrogen bond. International Union of Crystallography 2013-01-19 /pmc/articles/PMC3569208/ /pubmed/23424410 http://dx.doi.org/10.1107/S160053681300130X Text en © Eliseev et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Eliseev, Ivan I.
Bokach, Nadezhda A.
Haukka, Matti
Golenya, Irina A.
cis-Dichlorido(dimethyl sulfoxide-κS)(N,N,N′,N′-tetra­methyl­guanidine-κN′′)platinum(II)
title cis-Dichlorido(dimethyl sulfoxide-κS)(N,N,N′,N′-tetra­methyl­guanidine-κN′′)platinum(II)
title_full cis-Dichlorido(dimethyl sulfoxide-κS)(N,N,N′,N′-tetra­methyl­guanidine-κN′′)platinum(II)
title_fullStr cis-Dichlorido(dimethyl sulfoxide-κS)(N,N,N′,N′-tetra­methyl­guanidine-κN′′)platinum(II)
title_full_unstemmed cis-Dichlorido(dimethyl sulfoxide-κS)(N,N,N′,N′-tetra­methyl­guanidine-κN′′)platinum(II)
title_short cis-Dichlorido(dimethyl sulfoxide-κS)(N,N,N′,N′-tetra­methyl­guanidine-κN′′)platinum(II)
title_sort cis-dichlorido(dimethyl sulfoxide-κs)(n,n,n′,n′-tetra­methyl­guanidine-κn′′)platinum(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569208/
https://www.ncbi.nlm.nih.gov/pubmed/23424410
http://dx.doi.org/10.1107/S160053681300130X
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