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{Bis[N,N′-dicyclohexyl-N′′,N′′-bis(trimethylsilyl)guanidinato-κ(2) N,N′]neodymium(III)}di-μ-chlorido-[bis(tetrahydrofuran-κO)lithium]
In the title monomeric rare earth complex, [LiNd(C(19)H(40)N(3)Si(2))(2)Cl(2)(C(4)H(8)O)(2)], the [(Me(3)Si)(2)NC(NCy)(2)](2)Nd(+) (Me is methyl, Cy is cyclohexyl) and Li(THF)(2) (+) units (THF is tetrahydrofuran) are connected by two bridging Cl atoms. The Nd(3+) ion is coordinated by two guani...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569210/ https://www.ncbi.nlm.nih.gov/pubmed/23424412 http://dx.doi.org/10.1107/S160053681300158X |
Sumario: | In the title monomeric rare earth complex, [LiNd(C(19)H(40)N(3)Si(2))(2)Cl(2)(C(4)H(8)O)(2)], the [(Me(3)Si)(2)NC(NCy)(2)](2)Nd(+) (Me is methyl, Cy is cyclohexyl) and Li(THF)(2) (+) units (THF is tetrahydrofuran) are connected by two bridging Cl atoms. The Nd(3+) ion is coordinated by two guanidinate ligands and two Cl atoms, forming a distorted chelating octahedral geometry. The Li(+) ion is four-coordinated by two Cl atoms and two O atoms from THF molecules in a distorted tetrahedral geometry. |
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