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{Bis[N,N′-dicyclo­hexyl-N′′,N′′-bis­(tri­meth­yl­sil­yl)guanidinato-κ(2) N,N′]neo­dymium(III)}di-μ-chlorido-[bis­(tetra­hydro­furan-κO)lithium]

In the title monomeric rare earth complex, [LiNd(C(19)H(40)N(3)Si(2))(2)Cl(2)(C(4)H(8)O)(2)], the [(Me(3)Si)(2)NC(NCy)(2)](2)Nd(+) (Me is methyl, Cy is cyclo­hex­yl) and Li(THF)(2) (+) units (THF is tetra­hydro­furan) are connected by two bridging Cl atoms. The Nd(3+) ion is coordinated by two guani...

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Detalles Bibliográficos
Autores principales: Chi, Shu-Hui, Chen, Jue
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569210/
https://www.ncbi.nlm.nih.gov/pubmed/23424412
http://dx.doi.org/10.1107/S160053681300158X
Descripción
Sumario:In the title monomeric rare earth complex, [LiNd(C(19)H(40)N(3)Si(2))(2)Cl(2)(C(4)H(8)O)(2)], the [(Me(3)Si)(2)NC(NCy)(2)](2)Nd(+) (Me is methyl, Cy is cyclo­hex­yl) and Li(THF)(2) (+) units (THF is tetra­hydro­furan) are connected by two bridging Cl atoms. The Nd(3+) ion is coordinated by two guanidinate ligands and two Cl atoms, forming a distorted chelating octa­hedral geometry. The Li(+) ion is four-coordinated by two Cl atoms and two O atoms from THF mol­ecules in a distorted tetra­hedral geometry.