{Bis[N,N′-dicyclo­hexyl-N′′,N′′-bis­(tri­meth­yl­sil­yl)guanidinato-κ(2) N,N′]neo­dymium(III)}di-μ-chlorido-[bis­(tetra­hydro­furan-κO)lithium]

In the title monomeric rare earth complex, [LiNd(C(19)H(40)N(3)Si(2))(2)Cl(2)(C(4)H(8)O)(2)], the [(Me(3)Si)(2)NC(NCy)(2)](2)Nd(+) (Me is methyl, Cy is cyclo­hex­yl) and Li(THF)(2) (+) units (THF is tetra­hydro­furan) are connected by two bridging Cl atoms. The Nd(3+) ion is coordinated by two guani...

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Detalles Bibliográficos
Autores principales: Chi, Shu-Hui, Chen, Jue
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569210/
https://www.ncbi.nlm.nih.gov/pubmed/23424412
http://dx.doi.org/10.1107/S160053681300158X
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author Chi, Shu-Hui
Chen, Jue
author_facet Chi, Shu-Hui
Chen, Jue
author_sort Chi, Shu-Hui
collection PubMed
description In the title monomeric rare earth complex, [LiNd(C(19)H(40)N(3)Si(2))(2)Cl(2)(C(4)H(8)O)(2)], the [(Me(3)Si)(2)NC(NCy)(2)](2)Nd(+) (Me is methyl, Cy is cyclo­hex­yl) and Li(THF)(2) (+) units (THF is tetra­hydro­furan) are connected by two bridging Cl atoms. The Nd(3+) ion is coordinated by two guanidinate ligands and two Cl atoms, forming a distorted chelating octa­hedral geometry. The Li(+) ion is four-coordinated by two Cl atoms and two O atoms from THF mol­ecules in a distorted tetra­hedral geometry.
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spelling pubmed-35692102013-02-19 {Bis[N,N′-dicyclo­hexyl-N′′,N′′-bis­(tri­meth­yl­sil­yl)guanidinato-κ(2) N,N′]neo­dymium(III)}di-μ-chlorido-[bis­(tetra­hydro­furan-κO)lithium] Chi, Shu-Hui Chen, Jue Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title monomeric rare earth complex, [LiNd(C(19)H(40)N(3)Si(2))(2)Cl(2)(C(4)H(8)O)(2)], the [(Me(3)Si)(2)NC(NCy)(2)](2)Nd(+) (Me is methyl, Cy is cyclo­hex­yl) and Li(THF)(2) (+) units (THF is tetra­hydro­furan) are connected by two bridging Cl atoms. The Nd(3+) ion is coordinated by two guanidinate ligands and two Cl atoms, forming a distorted chelating octa­hedral geometry. The Li(+) ion is four-coordinated by two Cl atoms and two O atoms from THF mol­ecules in a distorted tetra­hedral geometry. International Union of Crystallography 2013-01-23 /pmc/articles/PMC3569210/ /pubmed/23424412 http://dx.doi.org/10.1107/S160053681300158X Text en © Chi and Chen 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chi, Shu-Hui
Chen, Jue
{Bis[N,N′-dicyclo­hexyl-N′′,N′′-bis­(tri­meth­yl­sil­yl)guanidinato-κ(2) N,N′]neo­dymium(III)}di-μ-chlorido-[bis­(tetra­hydro­furan-κO)lithium]
title {Bis[N,N′-dicyclo­hexyl-N′′,N′′-bis­(tri­meth­yl­sil­yl)guanidinato-κ(2) N,N′]neo­dymium(III)}di-μ-chlorido-[bis­(tetra­hydro­furan-κO)lithium]
title_full {Bis[N,N′-dicyclo­hexyl-N′′,N′′-bis­(tri­meth­yl­sil­yl)guanidinato-κ(2) N,N′]neo­dymium(III)}di-μ-chlorido-[bis­(tetra­hydro­furan-κO)lithium]
title_fullStr {Bis[N,N′-dicyclo­hexyl-N′′,N′′-bis­(tri­meth­yl­sil­yl)guanidinato-κ(2) N,N′]neo­dymium(III)}di-μ-chlorido-[bis­(tetra­hydro­furan-κO)lithium]
title_full_unstemmed {Bis[N,N′-dicyclo­hexyl-N′′,N′′-bis­(tri­meth­yl­sil­yl)guanidinato-κ(2) N,N′]neo­dymium(III)}di-μ-chlorido-[bis­(tetra­hydro­furan-κO)lithium]
title_short {Bis[N,N′-dicyclo­hexyl-N′′,N′′-bis­(tri­meth­yl­sil­yl)guanidinato-κ(2) N,N′]neo­dymium(III)}di-μ-chlorido-[bis­(tetra­hydro­furan-κO)lithium]
title_sort {bis[n,n′-dicyclo­hexyl-n′′,n′′-bis­(tri­meth­yl­sil­yl)guanidinato-κ(2) n,n′]neo­dymium(iii)}di-μ-chlorido-[bis­(tetra­hydro­furan-κo)lithium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569210/
https://www.ncbi.nlm.nih.gov/pubmed/23424412
http://dx.doi.org/10.1107/S160053681300158X
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AT chenjue bisnndicyclohexylnnbistrimethylsilylguanidinatok2nnneodymiumiiidimchloridobistetrahydrofurankolithium

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