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Bis(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxyl­ato-κO)tetra­kis­(methanol-κO)calcium methanol tetra­solvate

In the title compound, [Ca(C(19)H(11)F(2)O(2))(2)(CH(3)OH)(4)]·4CH(3)OH, the Ca(2+) ion is located on an inversion centre and is hexa­coordinated by two O atoms of two 4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxyl­ate ligands and four O atoms of four methanol ligands, forming a CaO(6) polyhedron...

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Autores principales: Kim, Namseok, Noh, Heeso, Yoon, Sungho, Park, Chan Ryang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569211/
https://www.ncbi.nlm.nih.gov/pubmed/23424413
http://dx.doi.org/10.1107/S1600536813000044
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author Kim, Namseok
Noh, Heeso
Yoon, Sungho
Park, Chan Ryang
author_facet Kim, Namseok
Noh, Heeso
Yoon, Sungho
Park, Chan Ryang
author_sort Kim, Namseok
collection PubMed
description In the title compound, [Ca(C(19)H(11)F(2)O(2))(2)(CH(3)OH)(4)]·4CH(3)OH, the Ca(2+) ion is located on an inversion centre and is hexa­coordinated by two O atoms of two 4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxyl­ate ligands and four O atoms of four methanol ligands, forming a CaO(6) polyhedron with a slightly distorted octa­hedral coordination geometry. The Ca—O—C angle between the carboxyl­ate group and the calcium ion is 171.8 (2)°. Two types of inter­molecular hydrogen-bond inter­actions (C=O⋯H and O—H⋯O) between the carboxyl­ate ligand, the methanol solvent mol­ecules and the coordinating methanol ligands generate a two-dimensional network parallel to (001).
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spelling pubmed-35692112013-02-19 Bis(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxyl­ato-κO)tetra­kis­(methanol-κO)calcium methanol tetra­solvate Kim, Namseok Noh, Heeso Yoon, Sungho Park, Chan Ryang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ca(C(19)H(11)F(2)O(2))(2)(CH(3)OH)(4)]·4CH(3)OH, the Ca(2+) ion is located on an inversion centre and is hexa­coordinated by two O atoms of two 4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxyl­ate ligands and four O atoms of four methanol ligands, forming a CaO(6) polyhedron with a slightly distorted octa­hedral coordination geometry. The Ca—O—C angle between the carboxyl­ate group and the calcium ion is 171.8 (2)°. Two types of inter­molecular hydrogen-bond inter­actions (C=O⋯H and O—H⋯O) between the carboxyl­ate ligand, the methanol solvent mol­ecules and the coordinating methanol ligands generate a two-dimensional network parallel to (001). International Union of Crystallography 2013-01-23 /pmc/articles/PMC3569211/ /pubmed/23424413 http://dx.doi.org/10.1107/S1600536813000044 Text en © Kim et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kim, Namseok
Noh, Heeso
Yoon, Sungho
Park, Chan Ryang
Bis(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxyl­ato-κO)tetra­kis­(methanol-κO)calcium methanol tetra­solvate
title Bis(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxyl­ato-κO)tetra­kis­(methanol-κO)calcium methanol tetra­solvate
title_full Bis(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxyl­ato-κO)tetra­kis­(methanol-κO)calcium methanol tetra­solvate
title_fullStr Bis(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxyl­ato-κO)tetra­kis­(methanol-κO)calcium methanol tetra­solvate
title_full_unstemmed Bis(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxyl­ato-κO)tetra­kis­(methanol-κO)calcium methanol tetra­solvate
title_short Bis(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxyl­ato-κO)tetra­kis­(methanol-κO)calcium methanol tetra­solvate
title_sort bis(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxyl­ato-κo)tetra­kis­(methanol-κo)calcium methanol tetra­solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569211/
https://www.ncbi.nlm.nih.gov/pubmed/23424413
http://dx.doi.org/10.1107/S1600536813000044
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