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Bis(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κO)tetrakis(methanol-κO)calcium methanol tetrasolvate
In the title compound, [Ca(C(19)H(11)F(2)O(2))(2)(CH(3)OH)(4)]·4CH(3)OH, the Ca(2+) ion is located on an inversion centre and is hexacoordinated by two O atoms of two 4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylate ligands and four O atoms of four methanol ligands, forming a CaO(6) polyhedron...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569211/ https://www.ncbi.nlm.nih.gov/pubmed/23424413 http://dx.doi.org/10.1107/S1600536813000044 |
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author | Kim, Namseok Noh, Heeso Yoon, Sungho Park, Chan Ryang |
author_facet | Kim, Namseok Noh, Heeso Yoon, Sungho Park, Chan Ryang |
author_sort | Kim, Namseok |
collection | PubMed |
description | In the title compound, [Ca(C(19)H(11)F(2)O(2))(2)(CH(3)OH)(4)]·4CH(3)OH, the Ca(2+) ion is located on an inversion centre and is hexacoordinated by two O atoms of two 4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylate ligands and four O atoms of four methanol ligands, forming a CaO(6) polyhedron with a slightly distorted octahedral coordination geometry. The Ca—O—C angle between the carboxylate group and the calcium ion is 171.8 (2)°. Two types of intermolecular hydrogen-bond interactions (C=O⋯H and O—H⋯O) between the carboxylate ligand, the methanol solvent molecules and the coordinating methanol ligands generate a two-dimensional network parallel to (001). |
format | Online Article Text |
id | pubmed-3569211 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35692112013-02-19 Bis(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κO)tetrakis(methanol-κO)calcium methanol tetrasolvate Kim, Namseok Noh, Heeso Yoon, Sungho Park, Chan Ryang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ca(C(19)H(11)F(2)O(2))(2)(CH(3)OH)(4)]·4CH(3)OH, the Ca(2+) ion is located on an inversion centre and is hexacoordinated by two O atoms of two 4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylate ligands and four O atoms of four methanol ligands, forming a CaO(6) polyhedron with a slightly distorted octahedral coordination geometry. The Ca—O—C angle between the carboxylate group and the calcium ion is 171.8 (2)°. Two types of intermolecular hydrogen-bond interactions (C=O⋯H and O—H⋯O) between the carboxylate ligand, the methanol solvent molecules and the coordinating methanol ligands generate a two-dimensional network parallel to (001). International Union of Crystallography 2013-01-23 /pmc/articles/PMC3569211/ /pubmed/23424413 http://dx.doi.org/10.1107/S1600536813000044 Text en © Kim et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kim, Namseok Noh, Heeso Yoon, Sungho Park, Chan Ryang Bis(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κO)tetrakis(methanol-κO)calcium methanol tetrasolvate |
title | Bis(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κO)tetrakis(methanol-κO)calcium methanol tetrasolvate |
title_full | Bis(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κO)tetrakis(methanol-κO)calcium methanol tetrasolvate |
title_fullStr | Bis(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κO)tetrakis(methanol-κO)calcium methanol tetrasolvate |
title_full_unstemmed | Bis(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κO)tetrakis(methanol-κO)calcium methanol tetrasolvate |
title_short | Bis(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κO)tetrakis(methanol-κO)calcium methanol tetrasolvate |
title_sort | bis(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κo)tetrakis(methanol-κo)calcium methanol tetrasolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569211/ https://www.ncbi.nlm.nih.gov/pubmed/23424413 http://dx.doi.org/10.1107/S1600536813000044 |
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