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μ-Oxalato-bis[bis(triphenylphosphine)copper(I)] dichloromethane disolvate
The dinuclear molecule of the title compound, [Cu(2)(C(2)O(4))(C(18)H(15)P)(4)]·2CH(2)Cl(2), lies across an inversion center with a strictly planar bridging oxalate ligand coordinating two Cu(I) ions via two pairs of O atoms. Two triphenylphosphine ligands also coordinate each symmetry-related Cu(I...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569214/ https://www.ncbi.nlm.nih.gov/pubmed/23424416 http://dx.doi.org/10.1107/S1600536813002080 |
| Sumario: | The dinuclear molecule of the title compound, [Cu(2)(C(2)O(4))(C(18)H(15)P)(4)]·2CH(2)Cl(2), lies across an inversion center with a strictly planar bridging oxalate ligand coordinating two Cu(I) ions via two pairs of O atoms. Two triphenylphosphine ligands also coordinate each symmetry-related Cu(I) ion, resulting in a distorted tetrahedral geometry [O—Cu—O = 80.57 (5)° and P—Cu—P = 125.72 (2)°]. In the crystal, there are two dichloromethane solvent molecules for each dinuclear complex. |
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