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μ-Oxalato-bis[bis(triphenylphosphine)copper(I)] dichloromethane disolvate
The dinuclear molecule of the title compound, [Cu(2)(C(2)O(4))(C(18)H(15)P)(4)]·2CH(2)Cl(2), lies across an inversion center with a strictly planar bridging oxalate ligand coordinating two Cu(I) ions via two pairs of O atoms. Two triphenylphosphine ligands also coordinate each symmetry-related Cu(I...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569214/ https://www.ncbi.nlm.nih.gov/pubmed/23424416 http://dx.doi.org/10.1107/S1600536813002080 |
| _version_ | 1782258853554946048 |
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| author | Royappa, Andrew D. Golen, James A. Rheingold, Arnold L. Royappa, A. Timothy |
| author_facet | Royappa, Andrew D. Golen, James A. Rheingold, Arnold L. Royappa, A. Timothy |
| author_sort | Royappa, Andrew D. |
| collection | PubMed |
| description | The dinuclear molecule of the title compound, [Cu(2)(C(2)O(4))(C(18)H(15)P)(4)]·2CH(2)Cl(2), lies across an inversion center with a strictly planar bridging oxalate ligand coordinating two Cu(I) ions via two pairs of O atoms. Two triphenylphosphine ligands also coordinate each symmetry-related Cu(I) ion, resulting in a distorted tetrahedral geometry [O—Cu—O = 80.57 (5)° and P—Cu—P = 125.72 (2)°]. In the crystal, there are two dichloromethane solvent molecules for each dinuclear complex. |
| format | Online Article Text |
| id | pubmed-3569214 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-35692142013-02-19 μ-Oxalato-bis[bis(triphenylphosphine)copper(I)] dichloromethane disolvate Royappa, Andrew D. Golen, James A. Rheingold, Arnold L. Royappa, A. Timothy Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dinuclear molecule of the title compound, [Cu(2)(C(2)O(4))(C(18)H(15)P)(4)]·2CH(2)Cl(2), lies across an inversion center with a strictly planar bridging oxalate ligand coordinating two Cu(I) ions via two pairs of O atoms. Two triphenylphosphine ligands also coordinate each symmetry-related Cu(I) ion, resulting in a distorted tetrahedral geometry [O—Cu—O = 80.57 (5)° and P—Cu—P = 125.72 (2)°]. In the crystal, there are two dichloromethane solvent molecules for each dinuclear complex. International Union of Crystallography 2013-01-31 /pmc/articles/PMC3569214/ /pubmed/23424416 http://dx.doi.org/10.1107/S1600536813002080 Text en © Royappa et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Royappa, Andrew D. Golen, James A. Rheingold, Arnold L. Royappa, A. Timothy μ-Oxalato-bis[bis(triphenylphosphine)copper(I)] dichloromethane disolvate |
| title | μ-Oxalato-bis[bis(triphenylphosphine)copper(I)] dichloromethane disolvate
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| title_full | μ-Oxalato-bis[bis(triphenylphosphine)copper(I)] dichloromethane disolvate
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| title_fullStr | μ-Oxalato-bis[bis(triphenylphosphine)copper(I)] dichloromethane disolvate
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| title_full_unstemmed | μ-Oxalato-bis[bis(triphenylphosphine)copper(I)] dichloromethane disolvate
|
| title_short | μ-Oxalato-bis[bis(triphenylphosphine)copper(I)] dichloromethane disolvate
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| title_sort | μ-oxalato-bis[bis(triphenylphosphine)copper(i)] dichloromethane disolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569214/ https://www.ncbi.nlm.nih.gov/pubmed/23424416 http://dx.doi.org/10.1107/S1600536813002080 |
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