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Bis(2-amino-4-methyl­pyrimidin-1-ium) hexa­aqua­cobalt(II) disulfate dihydrate

In the title hydrated mixed-cation salt, (C(5)H(8)N(3))(2)[Co(H(2)O)(6)](SO(4))(2)·2H(2)O, the complete octa­hedral hexa­aqua complex cation is generated by crystallographic inversion symmetry. In the crystal, the components are linked by O—H⋯O and N—H⋯O hydrogen bonds, the latter, involving pyrimid...

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Detalles Bibliográficos
Autores principales: Mirzaei, M., Eshtiagh-Hosseini, H., Zarghami, S., Karrabi, Z., Saeedi, M., Mague, J. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569216/
https://www.ncbi.nlm.nih.gov/pubmed/23424418
http://dx.doi.org/10.1107/S1600536813002146
Descripción
Sumario:In the title hydrated mixed-cation salt, (C(5)H(8)N(3))(2)[Co(H(2)O)(6)](SO(4))(2)·2H(2)O, the complete octa­hedral hexa­aqua complex cation is generated by crystallographic inversion symmetry. In the crystal, the components are linked by O—H⋯O and N—H⋯O hydrogen bonds, the latter, involving pyrimidinium cations and sulfate anions, generating R (2) (2)(8) loops. These, together with π–π inter­actions between centrosymmetrically related pyrimidinium cations [centroid–centroid separation = 3.5460 (8) Å], lead to the formation of a three-dimensional network.