Bis(2-amino-4-methyl­pyrimidin-1-ium) hexa­aqua­cobalt(II) disulfate dihydrate

In the title hydrated mixed-cation salt, (C(5)H(8)N(3))(2)[Co(H(2)O)(6)](SO(4))(2)·2H(2)O, the complete octa­hedral hexa­aqua complex cation is generated by crystallographic inversion symmetry. In the crystal, the components are linked by O—H⋯O and N—H⋯O hydrogen bonds, the latter, involving pyrimid...

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Autores principales: Mirzaei, M., Eshtiagh-Hosseini, H., Zarghami, S., Karrabi, Z., Saeedi, M., Mague, J. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569216/
https://www.ncbi.nlm.nih.gov/pubmed/23424418
http://dx.doi.org/10.1107/S1600536813002146
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author Mirzaei, M.
Eshtiagh-Hosseini, H.
Zarghami, S.
Karrabi, Z.
Saeedi, M.
Mague, J. T.
author_facet Mirzaei, M.
Eshtiagh-Hosseini, H.
Zarghami, S.
Karrabi, Z.
Saeedi, M.
Mague, J. T.
author_sort Mirzaei, M.
collection PubMed
description In the title hydrated mixed-cation salt, (C(5)H(8)N(3))(2)[Co(H(2)O)(6)](SO(4))(2)·2H(2)O, the complete octa­hedral hexa­aqua complex cation is generated by crystallographic inversion symmetry. In the crystal, the components are linked by O—H⋯O and N—H⋯O hydrogen bonds, the latter, involving pyrimidinium cations and sulfate anions, generating R (2) (2)(8) loops. These, together with π–π inter­actions between centrosymmetrically related pyrimidinium cations [centroid–centroid separation = 3.5460 (8) Å], lead to the formation of a three-dimensional network.
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spelling pubmed-35692162013-02-19 Bis(2-amino-4-methyl­pyrimidin-1-ium) hexa­aqua­cobalt(II) disulfate dihydrate Mirzaei, M. Eshtiagh-Hosseini, H. Zarghami, S. Karrabi, Z. Saeedi, M. Mague, J. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title hydrated mixed-cation salt, (C(5)H(8)N(3))(2)[Co(H(2)O)(6)](SO(4))(2)·2H(2)O, the complete octa­hedral hexa­aqua complex cation is generated by crystallographic inversion symmetry. In the crystal, the components are linked by O—H⋯O and N—H⋯O hydrogen bonds, the latter, involving pyrimidinium cations and sulfate anions, generating R (2) (2)(8) loops. These, together with π–π inter­actions between centrosymmetrically related pyrimidinium cations [centroid–centroid separation = 3.5460 (8) Å], lead to the formation of a three-dimensional network. International Union of Crystallography 2013-01-31 /pmc/articles/PMC3569216/ /pubmed/23424418 http://dx.doi.org/10.1107/S1600536813002146 Text en © Mirzaei et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mirzaei, M.
Eshtiagh-Hosseini, H.
Zarghami, S.
Karrabi, Z.
Saeedi, M.
Mague, J. T.
Bis(2-amino-4-methyl­pyrimidin-1-ium) hexa­aqua­cobalt(II) disulfate dihydrate
title Bis(2-amino-4-methyl­pyrimidin-1-ium) hexa­aqua­cobalt(II) disulfate dihydrate
title_full Bis(2-amino-4-methyl­pyrimidin-1-ium) hexa­aqua­cobalt(II) disulfate dihydrate
title_fullStr Bis(2-amino-4-methyl­pyrimidin-1-ium) hexa­aqua­cobalt(II) disulfate dihydrate
title_full_unstemmed Bis(2-amino-4-methyl­pyrimidin-1-ium) hexa­aqua­cobalt(II) disulfate dihydrate
title_short Bis(2-amino-4-methyl­pyrimidin-1-ium) hexa­aqua­cobalt(II) disulfate dihydrate
title_sort bis(2-amino-4-methyl­pyrimidin-1-ium) hexa­aqua­cobalt(ii) disulfate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569216/
https://www.ncbi.nlm.nih.gov/pubmed/23424418
http://dx.doi.org/10.1107/S1600536813002146
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AT zarghamis bis2amino4methylpyrimidin1iumhexaaquacobaltiidisulfatedihydrate
AT karrabiz bis2amino4methylpyrimidin1iumhexaaquacobaltiidisulfatedihydrate
AT saeedim bis2amino4methylpyrimidin1iumhexaaquacobaltiidisulfatedihydrate
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