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Bis(3-aminopyrazine-2-carboxylato-κ(2) N (1),O)diaquacobalt(II)
In the title compound, [Co(C(5)H(4)N(3)O(2))(2)(H(2)O)(2)], the Co(II) atom is situated on a twofold rotation axis and is N,O-chelated by two 3-aminopyrazine-2-carboxylate anions and additionally bonded to the O atoms of two water molecules, leading to a slightly distorted octahedral coordinatio...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569217/ https://www.ncbi.nlm.nih.gov/pubmed/23424419 http://dx.doi.org/10.1107/S1600536813002183 |
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author | Bouchene, Rafika Bouacida, Sofiane Berrah, Fadila Belhouas, Ratiba Merazig, Hocine |
author_facet | Bouchene, Rafika Bouacida, Sofiane Berrah, Fadila Belhouas, Ratiba Merazig, Hocine |
author_sort | Bouchene, Rafika |
collection | PubMed |
description | In the title compound, [Co(C(5)H(4)N(3)O(2))(2)(H(2)O)(2)], the Co(II) atom is situated on a twofold rotation axis and is N,O-chelated by two 3-aminopyrazine-2-carboxylate anions and additionally bonded to the O atoms of two water molecules, leading to a slightly distorted octahedral coordination environment. The crystal packing is dominated by intermolecular O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonding involving the water molecules and amino groups as donors and carboxylate O atoms, as well as the non-coordinating heterocyclic N atoms as acceptors, resulting in a three-dimensional network. An intramolecular N—H⋯O hydrogen bond is also observed. |
format | Online Article Text |
id | pubmed-3569217 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35692172013-02-19 Bis(3-aminopyrazine-2-carboxylato-κ(2) N (1),O)diaquacobalt(II) Bouchene, Rafika Bouacida, Sofiane Berrah, Fadila Belhouas, Ratiba Merazig, Hocine Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(5)H(4)N(3)O(2))(2)(H(2)O)(2)], the Co(II) atom is situated on a twofold rotation axis and is N,O-chelated by two 3-aminopyrazine-2-carboxylate anions and additionally bonded to the O atoms of two water molecules, leading to a slightly distorted octahedral coordination environment. The crystal packing is dominated by intermolecular O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonding involving the water molecules and amino groups as donors and carboxylate O atoms, as well as the non-coordinating heterocyclic N atoms as acceptors, resulting in a three-dimensional network. An intramolecular N—H⋯O hydrogen bond is also observed. International Union of Crystallography 2013-01-31 /pmc/articles/PMC3569217/ /pubmed/23424419 http://dx.doi.org/10.1107/S1600536813002183 Text en © Bouchene et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bouchene, Rafika Bouacida, Sofiane Berrah, Fadila Belhouas, Ratiba Merazig, Hocine Bis(3-aminopyrazine-2-carboxylato-κ(2) N (1),O)diaquacobalt(II) |
title | Bis(3-aminopyrazine-2-carboxylato-κ(2)
N
(1),O)diaquacobalt(II) |
title_full | Bis(3-aminopyrazine-2-carboxylato-κ(2)
N
(1),O)diaquacobalt(II) |
title_fullStr | Bis(3-aminopyrazine-2-carboxylato-κ(2)
N
(1),O)diaquacobalt(II) |
title_full_unstemmed | Bis(3-aminopyrazine-2-carboxylato-κ(2)
N
(1),O)diaquacobalt(II) |
title_short | Bis(3-aminopyrazine-2-carboxylato-κ(2)
N
(1),O)diaquacobalt(II) |
title_sort | bis(3-aminopyrazine-2-carboxylato-κ(2)
n
(1),o)diaquacobalt(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569217/ https://www.ncbi.nlm.nih.gov/pubmed/23424419 http://dx.doi.org/10.1107/S1600536813002183 |
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