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Bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) N (1),O)diaqua­cobalt(II)

In the title compound, [Co(C(5)H(4)N(3)O(2))(2)(H(2)O)(2)], the Co(II) atom is situated on a twofold rotation axis and is N,O-chelated by two 3-amino­pyrazine-2-carboxyl­ate anions and additionally bonded to the O atoms of two water mol­ecules, leading to a slightly distorted octa­hedral coordinatio...

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Autores principales: Bouchene, Rafika, Bouacida, Sofiane, Berrah, Fadila, Belhouas, Ratiba, Merazig, Hocine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569217/
https://www.ncbi.nlm.nih.gov/pubmed/23424419
http://dx.doi.org/10.1107/S1600536813002183
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author Bouchene, Rafika
Bouacida, Sofiane
Berrah, Fadila
Belhouas, Ratiba
Merazig, Hocine
author_facet Bouchene, Rafika
Bouacida, Sofiane
Berrah, Fadila
Belhouas, Ratiba
Merazig, Hocine
author_sort Bouchene, Rafika
collection PubMed
description In the title compound, [Co(C(5)H(4)N(3)O(2))(2)(H(2)O)(2)], the Co(II) atom is situated on a twofold rotation axis and is N,O-chelated by two 3-amino­pyrazine-2-carboxyl­ate anions and additionally bonded to the O atoms of two water mol­ecules, leading to a slightly distorted octa­hedral coordination environment. The crystal packing is dominated by inter­molecular O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonding involving the water mol­ecules and amino groups as donors and carboxyl­ate O atoms, as well as the non-coordinating heterocyclic N atoms as acceptors, resulting in a three-dimensional network. An intra­molecular N—H⋯O hydrogen bond is also observed.
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spelling pubmed-35692172013-02-19 Bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) N (1),O)diaqua­cobalt(II) Bouchene, Rafika Bouacida, Sofiane Berrah, Fadila Belhouas, Ratiba Merazig, Hocine Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(5)H(4)N(3)O(2))(2)(H(2)O)(2)], the Co(II) atom is situated on a twofold rotation axis and is N,O-chelated by two 3-amino­pyrazine-2-carboxyl­ate anions and additionally bonded to the O atoms of two water mol­ecules, leading to a slightly distorted octa­hedral coordination environment. The crystal packing is dominated by inter­molecular O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonding involving the water mol­ecules and amino groups as donors and carboxyl­ate O atoms, as well as the non-coordinating heterocyclic N atoms as acceptors, resulting in a three-dimensional network. An intra­molecular N—H⋯O hydrogen bond is also observed. International Union of Crystallography 2013-01-31 /pmc/articles/PMC3569217/ /pubmed/23424419 http://dx.doi.org/10.1107/S1600536813002183 Text en © Bouchene et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bouchene, Rafika
Bouacida, Sofiane
Berrah, Fadila
Belhouas, Ratiba
Merazig, Hocine
Bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) N (1),O)diaqua­cobalt(II)
title Bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) N (1),O)diaqua­cobalt(II)
title_full Bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) N (1),O)diaqua­cobalt(II)
title_fullStr Bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) N (1),O)diaqua­cobalt(II)
title_full_unstemmed Bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) N (1),O)diaqua­cobalt(II)
title_short Bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) N (1),O)diaqua­cobalt(II)
title_sort bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) n (1),o)diaqua­cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569217/
https://www.ncbi.nlm.nih.gov/pubmed/23424419
http://dx.doi.org/10.1107/S1600536813002183
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