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2-Chlorobenzene-1,4-diaminium bis(dihydrogenphosphate)
The asymmetric unit of the title salt, C(6)H(9)ClN(2) (2+)·2H(2)PO(4) (−), contains two dihydrogenphosphate anions and one 2-chlorobenzene-1,4-diaminium dication. The H(2)PO(4) (−) anions are interconnected through strong O—H⋯O hydrogen bonds to form two-dimensional infinite layers parallel to (00...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569226/ https://www.ncbi.nlm.nih.gov/pubmed/23424449 http://dx.doi.org/10.1107/S1600536812051434 |
Sumario: | The asymmetric unit of the title salt, C(6)H(9)ClN(2) (2+)·2H(2)PO(4) (−), contains two dihydrogenphosphate anions and one 2-chlorobenzene-1,4-diaminium dication. The H(2)PO(4) (−) anions are interconnected through strong O—H⋯O hydrogen bonds to form two-dimensional infinite layers parallel to (001). The organic entities are anchored to the inorganic layers through N—H⋯O hydrogen bonds, and through weak C—Cl⋯O halogen bonds [3.159 (2) Å, 140.48 (7)°]. No π–π stacking interactions between neighboring aromatic rings or C—H⋯π interactions towards them are observed. Minor disorder is observed for the Cl atom and one hydroxy group [minor-component occupancy = 3.29 (9)%]. |
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