2-Chloro­benzene-1,4-diaminium bis­(dihydrogenphosphate)

The asymmetric unit of the title salt, C(6)H(9)ClN(2) (2+)·2H(2)PO(4) (−), contains two dihydrogenphosphate anions and one 2-chloro­benzene-1,4-diaminium dication. The H(2)PO(4) (−) anions are inter­connected through strong O—H⋯O hydrogen bonds to form two-dimensional infinite layers parallel to (00...

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Autores principales: Mrad, Mohamed Lahbib, Zeller, Matthias, Rzaigui, Mohamed, Ben Nasr, Cherif
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569226/
https://www.ncbi.nlm.nih.gov/pubmed/23424449
http://dx.doi.org/10.1107/S1600536812051434
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author Mrad, Mohamed Lahbib
Zeller, Matthias
Rzaigui, Mohamed
Ben Nasr, Cherif
author_facet Mrad, Mohamed Lahbib
Zeller, Matthias
Rzaigui, Mohamed
Ben Nasr, Cherif
author_sort Mrad, Mohamed Lahbib
collection PubMed
description The asymmetric unit of the title salt, C(6)H(9)ClN(2) (2+)·2H(2)PO(4) (−), contains two dihydrogenphosphate anions and one 2-chloro­benzene-1,4-diaminium dication. The H(2)PO(4) (−) anions are inter­connected through strong O—H⋯O hydrogen bonds to form two-dimensional infinite layers parallel to (001). The organic entities are anchored to the inorganic layers through N—H⋯O hydrogen bonds, and through weak C—Cl⋯O halogen bonds [3.159 (2) Å, 140.48 (7)°]. No π–π stacking inter­actions between neighboring aromatic rings or C—H⋯π inter­actions towards them are observed. Minor disorder is observed for the Cl atom and one hy­droxy group [minor-component occupancy = 3.29 (9)%].
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spelling pubmed-35692262013-02-19 2-Chloro­benzene-1,4-diaminium bis­(dihydrogenphosphate) Mrad, Mohamed Lahbib Zeller, Matthias Rzaigui, Mohamed Ben Nasr, Cherif Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title salt, C(6)H(9)ClN(2) (2+)·2H(2)PO(4) (−), contains two dihydrogenphosphate anions and one 2-chloro­benzene-1,4-diaminium dication. The H(2)PO(4) (−) anions are inter­connected through strong O—H⋯O hydrogen bonds to form two-dimensional infinite layers parallel to (001). The organic entities are anchored to the inorganic layers through N—H⋯O hydrogen bonds, and through weak C—Cl⋯O halogen bonds [3.159 (2) Å, 140.48 (7)°]. No π–π stacking inter­actions between neighboring aromatic rings or C—H⋯π inter­actions towards them are observed. Minor disorder is observed for the Cl atom and one hy­droxy group [minor-component occupancy = 3.29 (9)%]. International Union of Crystallography 2013-01-04 /pmc/articles/PMC3569226/ /pubmed/23424449 http://dx.doi.org/10.1107/S1600536812051434 Text en © Mrad et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mrad, Mohamed Lahbib
Zeller, Matthias
Rzaigui, Mohamed
Ben Nasr, Cherif
2-Chloro­benzene-1,4-diaminium bis­(dihydrogenphosphate)
title 2-Chloro­benzene-1,4-diaminium bis­(dihydrogenphosphate)
title_full 2-Chloro­benzene-1,4-diaminium bis­(dihydrogenphosphate)
title_fullStr 2-Chloro­benzene-1,4-diaminium bis­(dihydrogenphosphate)
title_full_unstemmed 2-Chloro­benzene-1,4-diaminium bis­(dihydrogenphosphate)
title_short 2-Chloro­benzene-1,4-diaminium bis­(dihydrogenphosphate)
title_sort 2-chloro­benzene-1,4-diaminium bis­(dihydrogenphosphate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569226/
https://www.ncbi.nlm.nih.gov/pubmed/23424449
http://dx.doi.org/10.1107/S1600536812051434
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AT zellermatthias 2chlorobenzene14diaminiumbisdihydrogenphosphate
AT rzaiguimohamed 2chlorobenzene14diaminiumbisdihydrogenphosphate
AT bennasrcherif 2chlorobenzene14diaminiumbisdihydrogenphosphate

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