1-{(Z)-[2-Meth­oxy-5-(trifluoro­meth­yl)anilino]methyl­idene}naphthalen-2(1H)-one

The title compound, C(19)H(14)F(3)NO(2), crystallizes in the keto–amine tautomeric form, with a strong intra­molecular N—H⋯O hydrogen bond. The mol­ecule is almost planar; the dihedral angle between the naphthalene ring system and the benzene ring is 4.60 (7)°. In the crystal, mol­ecules are linked...

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Autores principales: Kargılı, Hakan, Alaman Ağar, Ayşen, Alpaslan, Gökhan, Büyükgüngör, Orhan, Erdönmez, Ahmet
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569228/
https://www.ncbi.nlm.nih.gov/pubmed/23424451
http://dx.doi.org/10.1107/S1600536812051410
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author Kargılı, Hakan
Alaman Ağar, Ayşen
Alpaslan, Gökhan
Büyükgüngör, Orhan
Erdönmez, Ahmet
author_facet Kargılı, Hakan
Alaman Ağar, Ayşen
Alpaslan, Gökhan
Büyükgüngör, Orhan
Erdönmez, Ahmet
author_sort Kargılı, Hakan
collection PubMed
description The title compound, C(19)H(14)F(3)NO(2), crystallizes in the keto–amine tautomeric form, with a strong intra­molecular N—H⋯O hydrogen bond. The mol­ecule is almost planar; the dihedral angle between the naphthalene ring system and the benzene ring is 4.60 (7)°. In the crystal, mol­ecules are linked into chains along the c axis by C—H⋯O hydrogen bonds. The F atoms of the trifluoro­methyl group are disordered over two positions with refined site occupancies of 0.668 (9) and 0.332 (9).
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spelling pubmed-35692282013-02-19 1-{(Z)-[2-Meth­oxy-5-(trifluoro­meth­yl)anilino]methyl­idene}naphthalen-2(1H)-one Kargılı, Hakan Alaman Ağar, Ayşen Alpaslan, Gökhan Büyükgüngör, Orhan Erdönmez, Ahmet Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(19)H(14)F(3)NO(2), crystallizes in the keto–amine tautomeric form, with a strong intra­molecular N—H⋯O hydrogen bond. The mol­ecule is almost planar; the dihedral angle between the naphthalene ring system and the benzene ring is 4.60 (7)°. In the crystal, mol­ecules are linked into chains along the c axis by C—H⋯O hydrogen bonds. The F atoms of the trifluoro­methyl group are disordered over two positions with refined site occupancies of 0.668 (9) and 0.332 (9). International Union of Crystallography 2013-01-04 /pmc/articles/PMC3569228/ /pubmed/23424451 http://dx.doi.org/10.1107/S1600536812051410 Text en © Kargılı et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kargılı, Hakan
Alaman Ağar, Ayşen
Alpaslan, Gökhan
Büyükgüngör, Orhan
Erdönmez, Ahmet
1-{(Z)-[2-Meth­oxy-5-(trifluoro­meth­yl)anilino]methyl­idene}naphthalen-2(1H)-one
title 1-{(Z)-[2-Meth­oxy-5-(trifluoro­meth­yl)anilino]methyl­idene}naphthalen-2(1H)-one
title_full 1-{(Z)-[2-Meth­oxy-5-(trifluoro­meth­yl)anilino]methyl­idene}naphthalen-2(1H)-one
title_fullStr 1-{(Z)-[2-Meth­oxy-5-(trifluoro­meth­yl)anilino]methyl­idene}naphthalen-2(1H)-one
title_full_unstemmed 1-{(Z)-[2-Meth­oxy-5-(trifluoro­meth­yl)anilino]methyl­idene}naphthalen-2(1H)-one
title_short 1-{(Z)-[2-Meth­oxy-5-(trifluoro­meth­yl)anilino]methyl­idene}naphthalen-2(1H)-one
title_sort 1-{(z)-[2-meth­oxy-5-(trifluoro­meth­yl)anilino]methyl­idene}naphthalen-2(1h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569228/
https://www.ncbi.nlm.nih.gov/pubmed/23424451
http://dx.doi.org/10.1107/S1600536812051410
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