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(Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithioate
In the title compound, C(16)H(15)N(3)S(2), the central C(2)N(2)S(2) residue is planar (r.m.s. deviation = 0.045 Å) and the pyridyl and benzene rings are inclined and approximately coplanar to this plane, respectively [dihedral angles = 72.85 (9) and 10.73 (9)°], so that, overall, the molecule adopt...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569232/ https://www.ncbi.nlm.nih.gov/pubmed/23424455 http://dx.doi.org/10.1107/S1600536812051537 |
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author | Low, May Lee Ravoof, Thahira Begum S. A. Tahir, Mohamed Ibrahim Mohamed Crouse, Karen A. Tiekink, Edward R. T. |
author_facet | Low, May Lee Ravoof, Thahira Begum S. A. Tahir, Mohamed Ibrahim Mohamed Crouse, Karen A. Tiekink, Edward R. T. |
author_sort | Low, May Lee |
collection | PubMed |
description | In the title compound, C(16)H(15)N(3)S(2), the central C(2)N(2)S(2) residue is planar (r.m.s. deviation = 0.045 Å) and the pyridyl and benzene rings are inclined and approximately coplanar to this plane, respectively [dihedral angles = 72.85 (9) and 10.73 (9)°], so that, overall, the molecule adopts an L-shape. The conformation about each of the N=C [1.290 (3) Å] and C=C [1.340 (3) Å] bonds is E. Supramolecular chains along [1-10] are stabilized by N—H⋯N(pyridine) hydrogen bonding and these are connected into a double layer that stacks along the c-axis direction by C—H⋯π(pyridine) interactions. |
format | Online Article Text |
id | pubmed-3569232 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35692322013-02-19 (Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithioate Low, May Lee Ravoof, Thahira Begum S. A. Tahir, Mohamed Ibrahim Mohamed Crouse, Karen A. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(15)N(3)S(2), the central C(2)N(2)S(2) residue is planar (r.m.s. deviation = 0.045 Å) and the pyridyl and benzene rings are inclined and approximately coplanar to this plane, respectively [dihedral angles = 72.85 (9) and 10.73 (9)°], so that, overall, the molecule adopts an L-shape. The conformation about each of the N=C [1.290 (3) Å] and C=C [1.340 (3) Å] bonds is E. Supramolecular chains along [1-10] are stabilized by N—H⋯N(pyridine) hydrogen bonding and these are connected into a double layer that stacks along the c-axis direction by C—H⋯π(pyridine) interactions. International Union of Crystallography 2013-01-04 /pmc/articles/PMC3569232/ /pubmed/23424455 http://dx.doi.org/10.1107/S1600536812051537 Text en © Low et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Low, May Lee Ravoof, Thahira Begum S. A. Tahir, Mohamed Ibrahim Mohamed Crouse, Karen A. Tiekink, Edward R. T. (Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithioate |
title | (Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithioate |
title_full | (Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithioate |
title_fullStr | (Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithioate |
title_full_unstemmed | (Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithioate |
title_short | (Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithioate |
title_sort | (pyridin-4-yl)methyl n′-(3-phenylallylidene)hydrazinecarbodithioate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569232/ https://www.ncbi.nlm.nih.gov/pubmed/23424455 http://dx.doi.org/10.1107/S1600536812051537 |
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