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(Pyridin-4-yl)methyl N′-(3-phenyl­allyl­idene)hydrazinecarbodithio­ate

In the title compound, C(16)H(15)N(3)S(2), the central C(2)N(2)S(2) residue is planar (r.m.s. deviation = 0.045 Å) and the pyridyl and benzene rings are inclined and approximately coplanar to this plane, respectively [dihedral angles = 72.85 (9) and 10.73 (9)°], so that, overall, the mol­ecule adopt...

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Autores principales: Low, May Lee, Ravoof, Thahira Begum S. A., Tahir, Mohamed Ibrahim Mohamed, Crouse, Karen A., Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569232/
https://www.ncbi.nlm.nih.gov/pubmed/23424455
http://dx.doi.org/10.1107/S1600536812051537
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author Low, May Lee
Ravoof, Thahira Begum S. A.
Tahir, Mohamed Ibrahim Mohamed
Crouse, Karen A.
Tiekink, Edward R. T.
author_facet Low, May Lee
Ravoof, Thahira Begum S. A.
Tahir, Mohamed Ibrahim Mohamed
Crouse, Karen A.
Tiekink, Edward R. T.
author_sort Low, May Lee
collection PubMed
description In the title compound, C(16)H(15)N(3)S(2), the central C(2)N(2)S(2) residue is planar (r.m.s. deviation = 0.045 Å) and the pyridyl and benzene rings are inclined and approximately coplanar to this plane, respectively [dihedral angles = 72.85 (9) and 10.73 (9)°], so that, overall, the mol­ecule adopts an L-shape. The conformation about each of the N=C [1.290 (3) Å] and C=C [1.340 (3) Å] bonds is E. Supra­molecular chains along [1-10] are stabilized by N—H⋯N(pyridine) hydrogen bonding and these are connected into a double layer that stacks along the c-axis direction by C—H⋯π(pyridine) inter­actions.
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spelling pubmed-35692322013-02-19 (Pyridin-4-yl)methyl N′-(3-phenyl­allyl­idene)hydrazinecarbodithio­ate Low, May Lee Ravoof, Thahira Begum S. A. Tahir, Mohamed Ibrahim Mohamed Crouse, Karen A. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(15)N(3)S(2), the central C(2)N(2)S(2) residue is planar (r.m.s. deviation = 0.045 Å) and the pyridyl and benzene rings are inclined and approximately coplanar to this plane, respectively [dihedral angles = 72.85 (9) and 10.73 (9)°], so that, overall, the mol­ecule adopts an L-shape. The conformation about each of the N=C [1.290 (3) Å] and C=C [1.340 (3) Å] bonds is E. Supra­molecular chains along [1-10] are stabilized by N—H⋯N(pyridine) hydrogen bonding and these are connected into a double layer that stacks along the c-axis direction by C—H⋯π(pyridine) inter­actions. International Union of Crystallography 2013-01-04 /pmc/articles/PMC3569232/ /pubmed/23424455 http://dx.doi.org/10.1107/S1600536812051537 Text en © Low et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Low, May Lee
Ravoof, Thahira Begum S. A.
Tahir, Mohamed Ibrahim Mohamed
Crouse, Karen A.
Tiekink, Edward R. T.
(Pyridin-4-yl)methyl N′-(3-phenyl­allyl­idene)hydrazinecarbodithio­ate
title (Pyridin-4-yl)methyl N′-(3-phenyl­allyl­idene)hydrazinecarbodithio­ate
title_full (Pyridin-4-yl)methyl N′-(3-phenyl­allyl­idene)hydrazinecarbodithio­ate
title_fullStr (Pyridin-4-yl)methyl N′-(3-phenyl­allyl­idene)hydrazinecarbodithio­ate
title_full_unstemmed (Pyridin-4-yl)methyl N′-(3-phenyl­allyl­idene)hydrazinecarbodithio­ate
title_short (Pyridin-4-yl)methyl N′-(3-phenyl­allyl­idene)hydrazinecarbodithio­ate
title_sort (pyridin-4-yl)methyl n′-(3-phenyl­allyl­idene)hydrazinecarbodithio­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569232/
https://www.ncbi.nlm.nih.gov/pubmed/23424455
http://dx.doi.org/10.1107/S1600536812051537
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