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4-[Amino(3-methylphenyl)methylidene]-2-(3-methylphenyl)-1H-imidazol-5(4H)-one ethanol hemisolvate
In the title compound, C(18)H(17)N(3)O·0.5C(2)H(5)OH, the dihedral angles between the central imidazole rings and the pendant benzene rings are 42.06 (15) and 2.01 (16)° in one asymmetric molecule and 47.91 (15) and 7.31 (14)° in the other. An intramolecular N—H⋯O hydrogen bond occurs in each imid...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569236/ https://www.ncbi.nlm.nih.gov/pubmed/23424459 http://dx.doi.org/10.1107/S160053681205163X |
| _version_ | 1782258858891149312 |
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| author | Prabhuswamy, M. Madan Kumar, S. Muneer, C. P. Shafi, P. M. Lokanath, N. K. |
| author_facet | Prabhuswamy, M. Madan Kumar, S. Muneer, C. P. Shafi, P. M. Lokanath, N. K. |
| author_sort | Prabhuswamy, M. |
| collection | PubMed |
| description | In the title compound, C(18)H(17)N(3)O·0.5C(2)H(5)OH, the dihedral angles between the central imidazole rings and the pendant benzene rings are 42.06 (15) and 2.01 (16)° in one asymmetric molecule and 47.91 (15) and 7.31 (14)° in the other. An intramolecular N—H⋯O hydrogen bond occurs in each imidazole molecule. In the crystal, the components are connected by O—H⋯N, N—H⋯O, C—H⋯O and N—H⋯N hydrogen bonds. Weak aromatic π–π interactions also occur [shortest centroid–centroid distance = 3.684 (3) Å]. |
| format | Online Article Text |
| id | pubmed-3569236 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-35692362013-02-19 4-[Amino(3-methylphenyl)methylidene]-2-(3-methylphenyl)-1H-imidazol-5(4H)-one ethanol hemisolvate Prabhuswamy, M. Madan Kumar, S. Muneer, C. P. Shafi, P. M. Lokanath, N. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(17)N(3)O·0.5C(2)H(5)OH, the dihedral angles between the central imidazole rings and the pendant benzene rings are 42.06 (15) and 2.01 (16)° in one asymmetric molecule and 47.91 (15) and 7.31 (14)° in the other. An intramolecular N—H⋯O hydrogen bond occurs in each imidazole molecule. In the crystal, the components are connected by O—H⋯N, N—H⋯O, C—H⋯O and N—H⋯N hydrogen bonds. Weak aromatic π–π interactions also occur [shortest centroid–centroid distance = 3.684 (3) Å]. International Union of Crystallography 2013-01-04 /pmc/articles/PMC3569236/ /pubmed/23424459 http://dx.doi.org/10.1107/S160053681205163X Text en © Prabhuswamy et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Prabhuswamy, M. Madan Kumar, S. Muneer, C. P. Shafi, P. M. Lokanath, N. K. 4-[Amino(3-methylphenyl)methylidene]-2-(3-methylphenyl)-1H-imidazol-5(4H)-one ethanol hemisolvate |
| title | 4-[Amino(3-methylphenyl)methylidene]-2-(3-methylphenyl)-1H-imidazol-5(4H)-one ethanol hemisolvate |
| title_full | 4-[Amino(3-methylphenyl)methylidene]-2-(3-methylphenyl)-1H-imidazol-5(4H)-one ethanol hemisolvate |
| title_fullStr | 4-[Amino(3-methylphenyl)methylidene]-2-(3-methylphenyl)-1H-imidazol-5(4H)-one ethanol hemisolvate |
| title_full_unstemmed | 4-[Amino(3-methylphenyl)methylidene]-2-(3-methylphenyl)-1H-imidazol-5(4H)-one ethanol hemisolvate |
| title_short | 4-[Amino(3-methylphenyl)methylidene]-2-(3-methylphenyl)-1H-imidazol-5(4H)-one ethanol hemisolvate |
| title_sort | 4-[amino(3-methylphenyl)methylidene]-2-(3-methylphenyl)-1h-imidazol-5(4h)-one ethanol hemisolvate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569236/ https://www.ncbi.nlm.nih.gov/pubmed/23424459 http://dx.doi.org/10.1107/S160053681205163X |
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