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Benzyl N-[(Z)-(1-methyl-2-sulfanyl­propyl­idene)amino]­carbamodithio­ate

The title compound, C(12)H(16)N(2)S(3), was obtained by the condensation reaction of S-benzyl dithio­carbazate and 3-mercaptobutan-2-one. The phenyl ring and thiol (SH) group are approximately perpendicular [S—C—C—C and N—C—C—S torsion angles = 67.8 (3) and 116.9 (2)°, respectively] to the rest of t...

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Detalles Bibliográficos
Autores principales: Break, Mohammed Khaled bin, Mehta, Sachin, Tahir, M. Ibrahim M., Crouse, Karen A., Khoo, Teng-Jin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569240/
https://www.ncbi.nlm.nih.gov/pubmed/23424463
http://dx.doi.org/10.1107/S1600536812051008
Descripción
Sumario:The title compound, C(12)H(16)N(2)S(3), was obtained by the condensation reaction of S-benzyl dithio­carbazate and 3-mercaptobutan-2-one. The phenyl ring and thiol (SH) group are approximately perpendicular [S—C—C—C and N—C—C—S torsion angles = 67.8 (3) and 116.9 (2)°, respectively] to the rest of the mol­ecule. In the crystal, mol­ecules are linked by weak S—H⋯S and N—H⋯S hydrogen bonds, π–π inter­actions between the benzene rings [centroid–centroid distance = 3.823 (2) Å] and C—H⋯π inter­actions.