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Benzyl N-[(Z)-(1-methyl-2-sulfanylpropylidene)amino]carbamodithioate
The title compound, C(12)H(16)N(2)S(3), was obtained by the condensation reaction of S-benzyl dithiocarbazate and 3-mercaptobutan-2-one. The phenyl ring and thiol (SH) group are approximately perpendicular [S—C—C—C and N—C—C—S torsion angles = 67.8 (3) and 116.9 (2)°, respectively] to the rest of t...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569240/ https://www.ncbi.nlm.nih.gov/pubmed/23424463 http://dx.doi.org/10.1107/S1600536812051008 |
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author | Break, Mohammed Khaled bin Mehta, Sachin Tahir, M. Ibrahim M. Crouse, Karen A. Khoo, Teng-Jin |
author_facet | Break, Mohammed Khaled bin Mehta, Sachin Tahir, M. Ibrahim M. Crouse, Karen A. Khoo, Teng-Jin |
author_sort | Break, Mohammed Khaled bin |
collection | PubMed |
description | The title compound, C(12)H(16)N(2)S(3), was obtained by the condensation reaction of S-benzyl dithiocarbazate and 3-mercaptobutan-2-one. The phenyl ring and thiol (SH) group are approximately perpendicular [S—C—C—C and N—C—C—S torsion angles = 67.8 (3) and 116.9 (2)°, respectively] to the rest of the molecule. In the crystal, molecules are linked by weak S—H⋯S and N—H⋯S hydrogen bonds, π–π interactions between the benzene rings [centroid–centroid distance = 3.823 (2) Å] and C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-3569240 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35692402013-02-19 Benzyl N-[(Z)-(1-methyl-2-sulfanylpropylidene)amino]carbamodithioate Break, Mohammed Khaled bin Mehta, Sachin Tahir, M. Ibrahim M. Crouse, Karen A. Khoo, Teng-Jin Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(12)H(16)N(2)S(3), was obtained by the condensation reaction of S-benzyl dithiocarbazate and 3-mercaptobutan-2-one. The phenyl ring and thiol (SH) group are approximately perpendicular [S—C—C—C and N—C—C—S torsion angles = 67.8 (3) and 116.9 (2)°, respectively] to the rest of the molecule. In the crystal, molecules are linked by weak S—H⋯S and N—H⋯S hydrogen bonds, π–π interactions between the benzene rings [centroid–centroid distance = 3.823 (2) Å] and C—H⋯π interactions. International Union of Crystallography 2013-01-04 /pmc/articles/PMC3569240/ /pubmed/23424463 http://dx.doi.org/10.1107/S1600536812051008 Text en © Break et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Break, Mohammed Khaled bin Mehta, Sachin Tahir, M. Ibrahim M. Crouse, Karen A. Khoo, Teng-Jin Benzyl N-[(Z)-(1-methyl-2-sulfanylpropylidene)amino]carbamodithioate |
title | Benzyl N-[(Z)-(1-methyl-2-sulfanylpropylidene)amino]carbamodithioate |
title_full | Benzyl N-[(Z)-(1-methyl-2-sulfanylpropylidene)amino]carbamodithioate |
title_fullStr | Benzyl N-[(Z)-(1-methyl-2-sulfanylpropylidene)amino]carbamodithioate |
title_full_unstemmed | Benzyl N-[(Z)-(1-methyl-2-sulfanylpropylidene)amino]carbamodithioate |
title_short | Benzyl N-[(Z)-(1-methyl-2-sulfanylpropylidene)amino]carbamodithioate |
title_sort | benzyl n-[(z)-(1-methyl-2-sulfanylpropylidene)amino]carbamodithioate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569240/ https://www.ncbi.nlm.nih.gov/pubmed/23424463 http://dx.doi.org/10.1107/S1600536812051008 |
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