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Benzyl N-[(Z)-(1-methyl-2-sulfanyl­propyl­idene)amino]­carbamodithio­ate

The title compound, C(12)H(16)N(2)S(3), was obtained by the condensation reaction of S-benzyl dithio­carbazate and 3-mercaptobutan-2-one. The phenyl ring and thiol (SH) group are approximately perpendicular [S—C—C—C and N—C—C—S torsion angles = 67.8 (3) and 116.9 (2)°, respectively] to the rest of t...

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Autores principales: Break, Mohammed Khaled bin, Mehta, Sachin, Tahir, M. Ibrahim M., Crouse, Karen A., Khoo, Teng-Jin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569240/
https://www.ncbi.nlm.nih.gov/pubmed/23424463
http://dx.doi.org/10.1107/S1600536812051008
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author Break, Mohammed Khaled bin
Mehta, Sachin
Tahir, M. Ibrahim M.
Crouse, Karen A.
Khoo, Teng-Jin
author_facet Break, Mohammed Khaled bin
Mehta, Sachin
Tahir, M. Ibrahim M.
Crouse, Karen A.
Khoo, Teng-Jin
author_sort Break, Mohammed Khaled bin
collection PubMed
description The title compound, C(12)H(16)N(2)S(3), was obtained by the condensation reaction of S-benzyl dithio­carbazate and 3-mercaptobutan-2-one. The phenyl ring and thiol (SH) group are approximately perpendicular [S—C—C—C and N—C—C—S torsion angles = 67.8 (3) and 116.9 (2)°, respectively] to the rest of the mol­ecule. In the crystal, mol­ecules are linked by weak S—H⋯S and N—H⋯S hydrogen bonds, π–π inter­actions between the benzene rings [centroid–centroid distance = 3.823 (2) Å] and C—H⋯π inter­actions.
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spelling pubmed-35692402013-02-19 Benzyl N-[(Z)-(1-methyl-2-sulfanyl­propyl­idene)amino]­carbamodithio­ate Break, Mohammed Khaled bin Mehta, Sachin Tahir, M. Ibrahim M. Crouse, Karen A. Khoo, Teng-Jin Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(12)H(16)N(2)S(3), was obtained by the condensation reaction of S-benzyl dithio­carbazate and 3-mercaptobutan-2-one. The phenyl ring and thiol (SH) group are approximately perpendicular [S—C—C—C and N—C—C—S torsion angles = 67.8 (3) and 116.9 (2)°, respectively] to the rest of the mol­ecule. In the crystal, mol­ecules are linked by weak S—H⋯S and N—H⋯S hydrogen bonds, π–π inter­actions between the benzene rings [centroid–centroid distance = 3.823 (2) Å] and C—H⋯π inter­actions. International Union of Crystallography 2013-01-04 /pmc/articles/PMC3569240/ /pubmed/23424463 http://dx.doi.org/10.1107/S1600536812051008 Text en © Break et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Break, Mohammed Khaled bin
Mehta, Sachin
Tahir, M. Ibrahim M.
Crouse, Karen A.
Khoo, Teng-Jin
Benzyl N-[(Z)-(1-methyl-2-sulfanyl­propyl­idene)amino]­carbamodithio­ate
title Benzyl N-[(Z)-(1-methyl-2-sulfanyl­propyl­idene)amino]­carbamodithio­ate
title_full Benzyl N-[(Z)-(1-methyl-2-sulfanyl­propyl­idene)amino]­carbamodithio­ate
title_fullStr Benzyl N-[(Z)-(1-methyl-2-sulfanyl­propyl­idene)amino]­carbamodithio­ate
title_full_unstemmed Benzyl N-[(Z)-(1-methyl-2-sulfanyl­propyl­idene)amino]­carbamodithio­ate
title_short Benzyl N-[(Z)-(1-methyl-2-sulfanyl­propyl­idene)amino]­carbamodithio­ate
title_sort benzyl n-[(z)-(1-methyl-2-sulfanyl­propyl­idene)amino]­carbamodithio­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569240/
https://www.ncbi.nlm.nih.gov/pubmed/23424463
http://dx.doi.org/10.1107/S1600536812051008
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