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2,4,6,8-Tetrakis(2-fluorophenyl)-3,7-diazabicyclo[3.3.1]nonan-9-one
The title compound, C(31)H(24)F(4)N(2)O, exists in a chair–boat conformation with an equatorial orientation of the 2-fluorophenyl groups on both sides of the secondary amino group of the chair form. The benzene rings in the ‘chair’ part are inclined to each other at 19.4 (1)°, while the equivalent...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569241/ https://www.ncbi.nlm.nih.gov/pubmed/23424464 http://dx.doi.org/10.1107/S1600536812051574 |
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author | Park, Dong Ho Ramkumar, V. Parthiban, P. |
author_facet | Park, Dong Ho Ramkumar, V. Parthiban, P. |
author_sort | Park, Dong Ho |
collection | PubMed |
description | The title compound, C(31)H(24)F(4)N(2)O, exists in a chair–boat conformation with an equatorial orientation of the 2-fluorophenyl groups on both sides of the secondary amino group of the chair form. The benzene rings in the ‘chair’ part are inclined to each other at 19.4 (1)°, while the equivalent angle between the benzene rings in the ‘boat’ part is 75.6 (1)°. One F atom was treated as disordered over two positions in a 0.838 (4):0.162 (4) ratio. In the crystal, N—H⋯O hydrogen bonds link the molecules into chains along [001] and these chains are held together via weak N—H⋯F and C—H⋯F interactions. |
format | Online Article Text |
id | pubmed-3569241 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35692412013-02-19 2,4,6,8-Tetrakis(2-fluorophenyl)-3,7-diazabicyclo[3.3.1]nonan-9-one Park, Dong Ho Ramkumar, V. Parthiban, P. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(31)H(24)F(4)N(2)O, exists in a chair–boat conformation with an equatorial orientation of the 2-fluorophenyl groups on both sides of the secondary amino group of the chair form. The benzene rings in the ‘chair’ part are inclined to each other at 19.4 (1)°, while the equivalent angle between the benzene rings in the ‘boat’ part is 75.6 (1)°. One F atom was treated as disordered over two positions in a 0.838 (4):0.162 (4) ratio. In the crystal, N—H⋯O hydrogen bonds link the molecules into chains along [001] and these chains are held together via weak N—H⋯F and C—H⋯F interactions. International Union of Crystallography 2013-01-04 /pmc/articles/PMC3569241/ /pubmed/23424464 http://dx.doi.org/10.1107/S1600536812051574 Text en © Park et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Park, Dong Ho Ramkumar, V. Parthiban, P. 2,4,6,8-Tetrakis(2-fluorophenyl)-3,7-diazabicyclo[3.3.1]nonan-9-one |
title | 2,4,6,8-Tetrakis(2-fluorophenyl)-3,7-diazabicyclo[3.3.1]nonan-9-one |
title_full | 2,4,6,8-Tetrakis(2-fluorophenyl)-3,7-diazabicyclo[3.3.1]nonan-9-one |
title_fullStr | 2,4,6,8-Tetrakis(2-fluorophenyl)-3,7-diazabicyclo[3.3.1]nonan-9-one |
title_full_unstemmed | 2,4,6,8-Tetrakis(2-fluorophenyl)-3,7-diazabicyclo[3.3.1]nonan-9-one |
title_short | 2,4,6,8-Tetrakis(2-fluorophenyl)-3,7-diazabicyclo[3.3.1]nonan-9-one |
title_sort | 2,4,6,8-tetrakis(2-fluorophenyl)-3,7-diazabicyclo[3.3.1]nonan-9-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569241/ https://www.ncbi.nlm.nih.gov/pubmed/23424464 http://dx.doi.org/10.1107/S1600536812051574 |
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