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2,4,6,8-Tetra­kis(2-fluoro­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one

The title compound, C(31)H(24)F(4)N(2)O, exists in a chair–boat conformation with an equatorial orientation of the 2-fluoro­phenyl groups on both sides of the secondary amino group of the chair form. The benzene rings in the ‘chair’ part are inclined to each other at 19.4 (1)°, while the equivalent...

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Detalles Bibliográficos
Autores principales: Park, Dong Ho, Ramkumar, V., Parthiban, P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569241/
https://www.ncbi.nlm.nih.gov/pubmed/23424464
http://dx.doi.org/10.1107/S1600536812051574
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author Park, Dong Ho
Ramkumar, V.
Parthiban, P.
author_facet Park, Dong Ho
Ramkumar, V.
Parthiban, P.
author_sort Park, Dong Ho
collection PubMed
description The title compound, C(31)H(24)F(4)N(2)O, exists in a chair–boat conformation with an equatorial orientation of the 2-fluoro­phenyl groups on both sides of the secondary amino group of the chair form. The benzene rings in the ‘chair’ part are inclined to each other at 19.4 (1)°, while the equivalent angle between the benzene rings in the ‘boat’ part is 75.6 (1)°. One F atom was treated as disordered over two positions in a 0.838 (4):0.162 (4) ratio. In the crystal, N—H⋯O hydrogen bonds link the mol­ecules into chains along [001] and these chains are held together via weak N—H⋯F and C—H⋯F inter­actions.
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spelling pubmed-35692412013-02-19 2,4,6,8-Tetra­kis(2-fluoro­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one Park, Dong Ho Ramkumar, V. Parthiban, P. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(31)H(24)F(4)N(2)O, exists in a chair–boat conformation with an equatorial orientation of the 2-fluoro­phenyl groups on both sides of the secondary amino group of the chair form. The benzene rings in the ‘chair’ part are inclined to each other at 19.4 (1)°, while the equivalent angle between the benzene rings in the ‘boat’ part is 75.6 (1)°. One F atom was treated as disordered over two positions in a 0.838 (4):0.162 (4) ratio. In the crystal, N—H⋯O hydrogen bonds link the mol­ecules into chains along [001] and these chains are held together via weak N—H⋯F and C—H⋯F inter­actions. International Union of Crystallography 2013-01-04 /pmc/articles/PMC3569241/ /pubmed/23424464 http://dx.doi.org/10.1107/S1600536812051574 Text en © Park et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Park, Dong Ho
Ramkumar, V.
Parthiban, P.
2,4,6,8-Tetra­kis(2-fluoro­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one
title 2,4,6,8-Tetra­kis(2-fluoro­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one
title_full 2,4,6,8-Tetra­kis(2-fluoro­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one
title_fullStr 2,4,6,8-Tetra­kis(2-fluoro­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one
title_full_unstemmed 2,4,6,8-Tetra­kis(2-fluoro­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one
title_short 2,4,6,8-Tetra­kis(2-fluoro­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one
title_sort 2,4,6,8-tetra­kis(2-fluoro­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569241/
https://www.ncbi.nlm.nih.gov/pubmed/23424464
http://dx.doi.org/10.1107/S1600536812051574
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