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Methyl 6-eth­oxy-3-phenyl-3a,4-dihydro-3H-chromeno[4,3-c]isoxazole-3a-car­boxylate

In the title compound, C(20)H(19)NO(5), the dihedral angle between the mean plane of the pyran ring (which has a half-chair conformation) and the benzene ring of the chromeno ring system is 7.21 (7)°. The dihedral angle between the mean plane of the chromeno ring system and the isoxazole ring is 21....

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Autores principales: Suresh, G., Srinivasan, J., Bakthadoss, M., Aravindhan, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569242/
https://www.ncbi.nlm.nih.gov/pubmed/23424465
http://dx.doi.org/10.1107/S1600536812051720
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author Suresh, G.
Srinivasan, J.
Bakthadoss, M.
Aravindhan, S.
author_facet Suresh, G.
Srinivasan, J.
Bakthadoss, M.
Aravindhan, S.
author_sort Suresh, G.
collection PubMed
description In the title compound, C(20)H(19)NO(5), the dihedral angle between the mean plane of the pyran ring (which has a half-chair conformation) and the benzene ring of the chromeno ring system is 7.21 (7)°. The dihedral angle between the mean plane of the chromeno ring system and the isoxazole ring is 21.78 (6)°, while the isoxazole ring forms a dihedral angle of 72.60 (8)° with the attached phenyl ring. In the crystal, mol­ecules are linked via pairs of C—H⋯O hydrogen bonds, forming inversion dimers with an R (2) (2)(10) ring motif. These dimers are linked via C—H⋯N hydrogen bonds, forming chains along [001].
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spelling pubmed-35692422013-02-19 Methyl 6-eth­oxy-3-phenyl-3a,4-dihydro-3H-chromeno[4,3-c]isoxazole-3a-car­boxylate Suresh, G. Srinivasan, J. Bakthadoss, M. Aravindhan, S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(19)NO(5), the dihedral angle between the mean plane of the pyran ring (which has a half-chair conformation) and the benzene ring of the chromeno ring system is 7.21 (7)°. The dihedral angle between the mean plane of the chromeno ring system and the isoxazole ring is 21.78 (6)°, while the isoxazole ring forms a dihedral angle of 72.60 (8)° with the attached phenyl ring. In the crystal, mol­ecules are linked via pairs of C—H⋯O hydrogen bonds, forming inversion dimers with an R (2) (2)(10) ring motif. These dimers are linked via C—H⋯N hydrogen bonds, forming chains along [001]. International Union of Crystallography 2013-01-04 /pmc/articles/PMC3569242/ /pubmed/23424465 http://dx.doi.org/10.1107/S1600536812051720 Text en © Suresh et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Suresh, G.
Srinivasan, J.
Bakthadoss, M.
Aravindhan, S.
Methyl 6-eth­oxy-3-phenyl-3a,4-dihydro-3H-chromeno[4,3-c]isoxazole-3a-car­boxylate
title Methyl 6-eth­oxy-3-phenyl-3a,4-dihydro-3H-chromeno[4,3-c]isoxazole-3a-car­boxylate
title_full Methyl 6-eth­oxy-3-phenyl-3a,4-dihydro-3H-chromeno[4,3-c]isoxazole-3a-car­boxylate
title_fullStr Methyl 6-eth­oxy-3-phenyl-3a,4-dihydro-3H-chromeno[4,3-c]isoxazole-3a-car­boxylate
title_full_unstemmed Methyl 6-eth­oxy-3-phenyl-3a,4-dihydro-3H-chromeno[4,3-c]isoxazole-3a-car­boxylate
title_short Methyl 6-eth­oxy-3-phenyl-3a,4-dihydro-3H-chromeno[4,3-c]isoxazole-3a-car­boxylate
title_sort methyl 6-eth­oxy-3-phenyl-3a,4-dihydro-3h-chromeno[4,3-c]isoxazole-3a-car­boxylate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569242/
https://www.ncbi.nlm.nih.gov/pubmed/23424465
http://dx.doi.org/10.1107/S1600536812051720
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