Diethyl [(2-chloro­anilino)(1,3-diphenyl-1H-pyrazol-4-yl)meth­yl]phospho­nate

In the title compound, C(26)H(27)ClN(3)O(3)P, the mean plane of the central pyrazole ring forms a dihedral angle of 71.37 (14)° with the chloro­phenyl ring. In the crystal, mol­ecules are linked by pairs of N—H⋯O hydrogen bonds, forming inversion dimers with R (2) (2)(10) ring motifs. The 3-phenyl r...

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Autores principales: Suresh, G., Nandakumar, A., Sabari, V., Perumal, P. T., Aravindhan, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569244/
https://www.ncbi.nlm.nih.gov/pubmed/23424467
http://dx.doi.org/10.1107/S1600536812051719
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author Suresh, G.
Nandakumar, A.
Sabari, V.
Perumal, P. T.
Aravindhan, S.
author_facet Suresh, G.
Nandakumar, A.
Sabari, V.
Perumal, P. T.
Aravindhan, S.
author_sort Suresh, G.
collection PubMed
description In the title compound, C(26)H(27)ClN(3)O(3)P, the mean plane of the central pyrazole ring forms a dihedral angle of 71.37 (14)° with the chloro­phenyl ring. In the crystal, mol­ecules are linked by pairs of N—H⋯O hydrogen bonds, forming inversion dimers with R (2) (2)(10) ring motifs. The 3-phenyl ring is disordered with four C atoms occupying two sets of sites with an occupancy ratio of 0.748 (4):0.252 (4).
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spelling pubmed-35692442013-02-19 Diethyl [(2-chloro­anilino)(1,3-diphenyl-1H-pyrazol-4-yl)meth­yl]phospho­nate Suresh, G. Nandakumar, A. Sabari, V. Perumal, P. T. Aravindhan, S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(27)ClN(3)O(3)P, the mean plane of the central pyrazole ring forms a dihedral angle of 71.37 (14)° with the chloro­phenyl ring. In the crystal, mol­ecules are linked by pairs of N—H⋯O hydrogen bonds, forming inversion dimers with R (2) (2)(10) ring motifs. The 3-phenyl ring is disordered with four C atoms occupying two sets of sites with an occupancy ratio of 0.748 (4):0.252 (4). International Union of Crystallography 2013-01-04 /pmc/articles/PMC3569244/ /pubmed/23424467 http://dx.doi.org/10.1107/S1600536812051719 Text en © Suresh et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Suresh, G.
Nandakumar, A.
Sabari, V.
Perumal, P. T.
Aravindhan, S.
Diethyl [(2-chloro­anilino)(1,3-diphenyl-1H-pyrazol-4-yl)meth­yl]phospho­nate
title Diethyl [(2-chloro­anilino)(1,3-diphenyl-1H-pyrazol-4-yl)meth­yl]phospho­nate
title_full Diethyl [(2-chloro­anilino)(1,3-diphenyl-1H-pyrazol-4-yl)meth­yl]phospho­nate
title_fullStr Diethyl [(2-chloro­anilino)(1,3-diphenyl-1H-pyrazol-4-yl)meth­yl]phospho­nate
title_full_unstemmed Diethyl [(2-chloro­anilino)(1,3-diphenyl-1H-pyrazol-4-yl)meth­yl]phospho­nate
title_short Diethyl [(2-chloro­anilino)(1,3-diphenyl-1H-pyrazol-4-yl)meth­yl]phospho­nate
title_sort diethyl [(2-chloro­anilino)(1,3-diphenyl-1h-pyrazol-4-yl)meth­yl]phospho­nate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569244/
https://www.ncbi.nlm.nih.gov/pubmed/23424467
http://dx.doi.org/10.1107/S1600536812051719
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