3,3′,5,5′-Tetra-tert-butyl-2′-hy­droxy-[1,1′-biphen­yl]-2-yl 4-methyl­benzene­sulfonate

In the title mol­ecule, C(37)H(48)O(4)S, the benzene rings in the biphenyl fragment are inclined to each other at 61.1 (1)°. The hy­droxy group is involved in a weak intra­molecular O—H⋯O(sulfonate) hydrogen bond. One tert-butyl group is disodered over two orientations in a 0.682 (17):0.318 (17) rat...

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Detalles Bibliográficos
Autores principales: Jian, Chunli, Zhang, Jinjin, Wang, Lei, Tang, Ning, Wu, Jincai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569248/
https://www.ncbi.nlm.nih.gov/pubmed/23424471
http://dx.doi.org/10.1107/S1600536812051938
Descripción
Sumario:In the title mol­ecule, C(37)H(48)O(4)S, the benzene rings in the biphenyl fragment are inclined to each other at 61.1 (1)°. The hy­droxy group is involved in a weak intra­molecular O—H⋯O(sulfonate) hydrogen bond. One tert-butyl group is disodered over two orientations in a 0.682 (17):0.318 (17) ratio. In the crystal, weak C—H⋯O hydrogen bonds link the mol­ecules into columns in direction [100].

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