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3,3′,5,5′-Tetra-tert-butyl-2′-hydroxy-[1,1′-biphenyl]-2-yl 4-methylbenzenesulfonate
In the title molecule, C(37)H(48)O(4)S, the benzene rings in the biphenyl fragment are inclined to each other at 61.1 (1)°. The hydroxy group is involved in a weak intramolecular O—H⋯O(sulfonate) hydrogen bond. One tert-butyl group is disodered over two orientations in a 0.682 (17):0.318 (17) rat...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569248/ https://www.ncbi.nlm.nih.gov/pubmed/23424471 http://dx.doi.org/10.1107/S1600536812051938 |
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author | Jian, Chunli Zhang, Jinjin Wang, Lei Tang, Ning Wu, Jincai |
author_facet | Jian, Chunli Zhang, Jinjin Wang, Lei Tang, Ning Wu, Jincai |
author_sort | Jian, Chunli |
collection | PubMed |
description | In the title molecule, C(37)H(48)O(4)S, the benzene rings in the biphenyl fragment are inclined to each other at 61.1 (1)°. The hydroxy group is involved in a weak intramolecular O—H⋯O(sulfonate) hydrogen bond. One tert-butyl group is disodered over two orientations in a 0.682 (17):0.318 (17) ratio. In the crystal, weak C—H⋯O hydrogen bonds link the molecules into columns in direction [100]. |
format | Online Article Text |
id | pubmed-3569248 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35692482013-02-19 3,3′,5,5′-Tetra-tert-butyl-2′-hydroxy-[1,1′-biphenyl]-2-yl 4-methylbenzenesulfonate Jian, Chunli Zhang, Jinjin Wang, Lei Tang, Ning Wu, Jincai Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(37)H(48)O(4)S, the benzene rings in the biphenyl fragment are inclined to each other at 61.1 (1)°. The hydroxy group is involved in a weak intramolecular O—H⋯O(sulfonate) hydrogen bond. One tert-butyl group is disodered over two orientations in a 0.682 (17):0.318 (17) ratio. In the crystal, weak C—H⋯O hydrogen bonds link the molecules into columns in direction [100]. International Union of Crystallography 2013-01-04 /pmc/articles/PMC3569248/ /pubmed/23424471 http://dx.doi.org/10.1107/S1600536812051938 Text en © Jian et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Jian, Chunli Zhang, Jinjin Wang, Lei Tang, Ning Wu, Jincai 3,3′,5,5′-Tetra-tert-butyl-2′-hydroxy-[1,1′-biphenyl]-2-yl 4-methylbenzenesulfonate |
title | 3,3′,5,5′-Tetra-tert-butyl-2′-hydroxy-[1,1′-biphenyl]-2-yl 4-methylbenzenesulfonate |
title_full | 3,3′,5,5′-Tetra-tert-butyl-2′-hydroxy-[1,1′-biphenyl]-2-yl 4-methylbenzenesulfonate |
title_fullStr | 3,3′,5,5′-Tetra-tert-butyl-2′-hydroxy-[1,1′-biphenyl]-2-yl 4-methylbenzenesulfonate |
title_full_unstemmed | 3,3′,5,5′-Tetra-tert-butyl-2′-hydroxy-[1,1′-biphenyl]-2-yl 4-methylbenzenesulfonate |
title_short | 3,3′,5,5′-Tetra-tert-butyl-2′-hydroxy-[1,1′-biphenyl]-2-yl 4-methylbenzenesulfonate |
title_sort | 3,3′,5,5′-tetra-tert-butyl-2′-hydroxy-[1,1′-biphenyl]-2-yl 4-methylbenzenesulfonate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569248/ https://www.ncbi.nlm.nih.gov/pubmed/23424471 http://dx.doi.org/10.1107/S1600536812051938 |
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