3-[2-Cyclo­propyl-1-(2-fluoro­phen­yl)-2-oxoeth­yl]-5-(4-methyl­sulfanyl­benzyl­idene)-1,3-thia­zolidine-2,4-dione

In the title compound, C(22)H(18)FNO(3)S(2), the five-membered thia­zolidine ring is planar (r.m.s. deviation = 0.003 Å) and forms dihedral angles of 70.2 (3), 73.16 (17) and 10.32 (14)° with the cyclo­propane, fluoro­benzene and methyl­thio­benzene rings, respectively. The sum of the bond angles ar...

Descripción completa

Detalles Bibliográficos
Autores principales: Suresh, J., Venkateshan, M., Ponnuchamy, S., Kumar, R. Ranjith, Lakshman, P. L. Nilantha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569250/
https://www.ncbi.nlm.nih.gov/pubmed/23424473
http://dx.doi.org/10.1107/S1600536812051987
_version_ 1782258862156414976
author Suresh, J.
Venkateshan, M.
Ponnuchamy, S.
Kumar, R. Ranjith
Lakshman, P. L. Nilantha
author_facet Suresh, J.
Venkateshan, M.
Ponnuchamy, S.
Kumar, R. Ranjith
Lakshman, P. L. Nilantha
author_sort Suresh, J.
collection PubMed
description In the title compound, C(22)H(18)FNO(3)S(2), the five-membered thia­zolidine ring is planar (r.m.s. deviation = 0.003 Å) and forms dihedral angles of 70.2 (3), 73.16 (17) and 10.32 (14)° with the cyclo­propane, fluoro­benzene and methyl­thio­benzene rings, respectively. The sum of the bond angles around the thia­zolidine ring N atom (359.6°) indicates sp (2) hybridization. The mol­ecular structure features intra­molecular C—H⋯S, C—H⋯F and C—H⋯O inter­actions. In the crystal, no significant inter­molecular contacts were apparent.
format Online
Article
Text
id pubmed-3569250
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-35692502013-02-19 3-[2-Cyclo­propyl-1-(2-fluoro­phen­yl)-2-oxoeth­yl]-5-(4-methyl­sulfanyl­benzyl­idene)-1,3-thia­zolidine-2,4-dione Suresh, J. Venkateshan, M. Ponnuchamy, S. Kumar, R. Ranjith Lakshman, P. L. Nilantha Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(22)H(18)FNO(3)S(2), the five-membered thia­zolidine ring is planar (r.m.s. deviation = 0.003 Å) and forms dihedral angles of 70.2 (3), 73.16 (17) and 10.32 (14)° with the cyclo­propane, fluoro­benzene and methyl­thio­benzene rings, respectively. The sum of the bond angles around the thia­zolidine ring N atom (359.6°) indicates sp (2) hybridization. The mol­ecular structure features intra­molecular C—H⋯S, C—H⋯F and C—H⋯O inter­actions. In the crystal, no significant inter­molecular contacts were apparent. International Union of Crystallography 2013-01-04 /pmc/articles/PMC3569250/ /pubmed/23424473 http://dx.doi.org/10.1107/S1600536812051987 Text en © Suresh et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Suresh, J.
Venkateshan, M.
Ponnuchamy, S.
Kumar, R. Ranjith
Lakshman, P. L. Nilantha
3-[2-Cyclo­propyl-1-(2-fluoro­phen­yl)-2-oxoeth­yl]-5-(4-methyl­sulfanyl­benzyl­idene)-1,3-thia­zolidine-2,4-dione
title 3-[2-Cyclo­propyl-1-(2-fluoro­phen­yl)-2-oxoeth­yl]-5-(4-methyl­sulfanyl­benzyl­idene)-1,3-thia­zolidine-2,4-dione
title_full 3-[2-Cyclo­propyl-1-(2-fluoro­phen­yl)-2-oxoeth­yl]-5-(4-methyl­sulfanyl­benzyl­idene)-1,3-thia­zolidine-2,4-dione
title_fullStr 3-[2-Cyclo­propyl-1-(2-fluoro­phen­yl)-2-oxoeth­yl]-5-(4-methyl­sulfanyl­benzyl­idene)-1,3-thia­zolidine-2,4-dione
title_full_unstemmed 3-[2-Cyclo­propyl-1-(2-fluoro­phen­yl)-2-oxoeth­yl]-5-(4-methyl­sulfanyl­benzyl­idene)-1,3-thia­zolidine-2,4-dione
title_short 3-[2-Cyclo­propyl-1-(2-fluoro­phen­yl)-2-oxoeth­yl]-5-(4-methyl­sulfanyl­benzyl­idene)-1,3-thia­zolidine-2,4-dione
title_sort 3-[2-cyclo­propyl-1-(2-fluoro­phen­yl)-2-oxoeth­yl]-5-(4-methyl­sulfanyl­benzyl­idene)-1,3-thia­zolidine-2,4-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569250/
https://www.ncbi.nlm.nih.gov/pubmed/23424473
http://dx.doi.org/10.1107/S1600536812051987
work_keys_str_mv AT sureshj 32cyclopropyl12fluorophenyl2oxoethyl54methylsulfanylbenzylidene13thiazolidine24dione
AT venkateshanm 32cyclopropyl12fluorophenyl2oxoethyl54methylsulfanylbenzylidene13thiazolidine24dione
AT ponnuchamys 32cyclopropyl12fluorophenyl2oxoethyl54methylsulfanylbenzylidene13thiazolidine24dione
AT kumarrranjith 32cyclopropyl12fluorophenyl2oxoethyl54methylsulfanylbenzylidene13thiazolidine24dione
AT lakshmanplnilantha 32cyclopropyl12fluorophenyl2oxoethyl54methylsulfanylbenzylidene13thiazolidine24dione

Ejemplares similares