(6-Meth­oxy-2-oxo-2H-chromen-4-yl)methyl morpholine-4-carbodithio­ate

In the title compound, C(16)H(17)NO(4)S(2), the 2H-chromene ring system is nearly planar, with a maximum deviation of 0.070 (1) Å, and the morpholine ring adopts a chair conformation; the bond-angle sum for its N atom is 357.9°. The dihedral angle between the the 2H-chromene ring and the best plane...

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Autores principales: Devarajegowda, H. C., Kumar, K. Mahesh, Seenivasa, S., Arunkashi, H. K., Kotresh, O.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569253/
https://www.ncbi.nlm.nih.gov/pubmed/23424476
http://dx.doi.org/10.1107/S1600536812051847
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author Devarajegowda, H. C.
Kumar, K. Mahesh
Seenivasa, S.
Arunkashi, H. K.
Kotresh, O.
author_facet Devarajegowda, H. C.
Kumar, K. Mahesh
Seenivasa, S.
Arunkashi, H. K.
Kotresh, O.
author_sort Devarajegowda, H. C.
collection PubMed
description In the title compound, C(16)H(17)NO(4)S(2), the 2H-chromene ring system is nearly planar, with a maximum deviation of 0.070 (1) Å, and the morpholine ring adopts a chair conformation; the bond-angle sum for its N atom is 357.9°. The dihedral angle between the the 2H-chromene ring and the best plane through the morpholine ring is 89.09 (6)°. An intra­molecular C—H⋯S hydrogen bond occurs. In the crystal, C—H⋯O hydrogen bonds generate R (2) (2)(8) rings and π–π inter­actions occur between fused benzene rings of the chromene system [shortest centroid–centroid distance = 3.5487 (8) Å].
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spelling pubmed-35692532013-02-19 (6-Meth­oxy-2-oxo-2H-chromen-4-yl)methyl morpholine-4-carbodithio­ate Devarajegowda, H. C. Kumar, K. Mahesh Seenivasa, S. Arunkashi, H. K. Kotresh, O. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(17)NO(4)S(2), the 2H-chromene ring system is nearly planar, with a maximum deviation of 0.070 (1) Å, and the morpholine ring adopts a chair conformation; the bond-angle sum for its N atom is 357.9°. The dihedral angle between the the 2H-chromene ring and the best plane through the morpholine ring is 89.09 (6)°. An intra­molecular C—H⋯S hydrogen bond occurs. In the crystal, C—H⋯O hydrogen bonds generate R (2) (2)(8) rings and π–π inter­actions occur between fused benzene rings of the chromene system [shortest centroid–centroid distance = 3.5487 (8) Å]. International Union of Crystallography 2013-01-09 /pmc/articles/PMC3569253/ /pubmed/23424476 http://dx.doi.org/10.1107/S1600536812051847 Text en © Devarajegowda et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Devarajegowda, H. C.
Kumar, K. Mahesh
Seenivasa, S.
Arunkashi, H. K.
Kotresh, O.
(6-Meth­oxy-2-oxo-2H-chromen-4-yl)methyl morpholine-4-carbodithio­ate
title (6-Meth­oxy-2-oxo-2H-chromen-4-yl)methyl morpholine-4-carbodithio­ate
title_full (6-Meth­oxy-2-oxo-2H-chromen-4-yl)methyl morpholine-4-carbodithio­ate
title_fullStr (6-Meth­oxy-2-oxo-2H-chromen-4-yl)methyl morpholine-4-carbodithio­ate
title_full_unstemmed (6-Meth­oxy-2-oxo-2H-chromen-4-yl)methyl morpholine-4-carbodithio­ate
title_short (6-Meth­oxy-2-oxo-2H-chromen-4-yl)methyl morpholine-4-carbodithio­ate
title_sort (6-meth­oxy-2-oxo-2h-chromen-4-yl)methyl morpholine-4-carbodithio­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569253/
https://www.ncbi.nlm.nih.gov/pubmed/23424476
http://dx.doi.org/10.1107/S1600536812051847
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