P,P-Bis[4-(dimethyl­amino)­phen­yl]-N,N-bis­(propan-2-yl)phosphinic amide

The mol­ecular structure of the title compound, C(22)H(34)N(3)OP, adopts a distorted tetra­hedral geometry at the P atom, with the most noticeable distortion being for the O—P—N angle [117.53 (10)°]. An effective cone angle of 187° was calculated for the compound. In the crystal, weak C—H⋯O inter­ac...

Descripción completa

Detalles Bibliográficos
Autores principales: Evans, Stephen J., Renison, C. Alicia, Williams, D. Bradley G., Muller, Alfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569256/
https://www.ncbi.nlm.nih.gov/pubmed/23424479
http://dx.doi.org/10.1107/S1600536812050398
Descripción
Sumario:The mol­ecular structure of the title compound, C(22)H(34)N(3)OP, adopts a distorted tetra­hedral geometry at the P atom, with the most noticeable distortion being for the O—P—N angle [117.53 (10)°]. An effective cone angle of 187° was calculated for the compound. In the crystal, weak C—H⋯O inter­actions create infinite chains along [100], whereas C—H⋯π inter­actions propagating in [001] generate a herringbone motif.

Ejemplares similares