P,P-Bis[4-(dimethyl­amino)­phen­yl]-N,N-bis­(propan-2-yl)phosphinic amide

The mol­ecular structure of the title compound, C(22)H(34)N(3)OP, adopts a distorted tetra­hedral geometry at the P atom, with the most noticeable distortion being for the O—P—N angle [117.53 (10)°]. An effective cone angle of 187° was calculated for the compound. In the crystal, weak C—H⋯O inter­ac...

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Detalles Bibliográficos
Autores principales: Evans, Stephen J., Renison, C. Alicia, Williams, D. Bradley G., Muller, Alfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569256/
https://www.ncbi.nlm.nih.gov/pubmed/23424479
http://dx.doi.org/10.1107/S1600536812050398
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author Evans, Stephen J.
Renison, C. Alicia
Williams, D. Bradley G.
Muller, Alfred
author_facet Evans, Stephen J.
Renison, C. Alicia
Williams, D. Bradley G.
Muller, Alfred
author_sort Evans, Stephen J.
collection PubMed
description The mol­ecular structure of the title compound, C(22)H(34)N(3)OP, adopts a distorted tetra­hedral geometry at the P atom, with the most noticeable distortion being for the O—P—N angle [117.53 (10)°]. An effective cone angle of 187° was calculated for the compound. In the crystal, weak C—H⋯O inter­actions create infinite chains along [100], whereas C—H⋯π inter­actions propagating in [001] generate a herringbone motif.
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spelling pubmed-35692562013-02-19 P,P-Bis[4-(dimethyl­amino)­phen­yl]-N,N-bis­(propan-2-yl)phosphinic amide Evans, Stephen J. Renison, C. Alicia Williams, D. Bradley G. Muller, Alfred Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecular structure of the title compound, C(22)H(34)N(3)OP, adopts a distorted tetra­hedral geometry at the P atom, with the most noticeable distortion being for the O—P—N angle [117.53 (10)°]. An effective cone angle of 187° was calculated for the compound. In the crystal, weak C—H⋯O inter­actions create infinite chains along [100], whereas C—H⋯π inter­actions propagating in [001] generate a herringbone motif. International Union of Crystallography 2013-01-09 /pmc/articles/PMC3569256/ /pubmed/23424479 http://dx.doi.org/10.1107/S1600536812050398 Text en © Evans et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Evans, Stephen J.
Renison, C. Alicia
Williams, D. Bradley G.
Muller, Alfred
P,P-Bis[4-(dimethyl­amino)­phen­yl]-N,N-bis­(propan-2-yl)phosphinic amide
title P,P-Bis[4-(dimethyl­amino)­phen­yl]-N,N-bis­(propan-2-yl)phosphinic amide
title_full P,P-Bis[4-(dimethyl­amino)­phen­yl]-N,N-bis­(propan-2-yl)phosphinic amide
title_fullStr P,P-Bis[4-(dimethyl­amino)­phen­yl]-N,N-bis­(propan-2-yl)phosphinic amide
title_full_unstemmed P,P-Bis[4-(dimethyl­amino)­phen­yl]-N,N-bis­(propan-2-yl)phosphinic amide
title_short P,P-Bis[4-(dimethyl­amino)­phen­yl]-N,N-bis­(propan-2-yl)phosphinic amide
title_sort p,p-bis[4-(dimethyl­amino)­phen­yl]-n,n-bis­(propan-2-yl)phosphinic amide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569256/
https://www.ncbi.nlm.nih.gov/pubmed/23424479
http://dx.doi.org/10.1107/S1600536812050398
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