Bis(4-meth­oxy­benzyl­ammonium) dihydrogen diphosphate

In the title compound, 2C(8)H(12)NO(+)·H(2)P(2)O(7) (2−), the linked PO(4) groups of the diphosphate anion are almost eclipsed and the P—O—P angle is 134.45 (7)°. In the crystal, infinite ribbons of H(2)P(2)O(7) (2−) anions propagate in [100], being linked by strong O—H⋯O hydrogen bonds. The 4-meth­...

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Detalles Bibliográficos
Autores principales: Elboulali, Adel, Akriche, Samah, Al-Deyab, Salem S., Rzaigui, Mohamed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569749/
https://www.ncbi.nlm.nih.gov/pubmed/23424495
http://dx.doi.org/10.1107/S1600536812051616
Descripción
Sumario:In the title compound, 2C(8)H(12)NO(+)·H(2)P(2)O(7) (2−), the linked PO(4) groups of the diphosphate anion are almost eclipsed and the P—O—P angle is 134.45 (7)°. In the crystal, infinite ribbons of H(2)P(2)O(7) (2−) anions propagate in [100], being linked by strong O—H⋯O hydrogen bonds. The 4-meth­oxy­benzyl­ammonium cations bond to the diphosphate chains by N—H⋯O and C—H⋯O links, and are themselves linked by C—H⋯π inter­actions.

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