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3-Methyl-1-tosyl-1H-indole-2-carbaldehyde

The title indole derivative, C(17)H(15)NO(3)S, crystallizes with two independent mol­ecules in the asymmetric unit. The benzene ring of the tosyl group is almost perpedicular to the indole ring in both mol­ecules, with inter­planar angles of 82.60 (5)° and 81.82 (6)°. The two mol­ecules are, as a co...

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Autores principales: Pradeep, Priyamvada, Khorasani, Sanaz, de Koning, Charles B., Fernandes, Manuel A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569754/
https://www.ncbi.nlm.nih.gov/pubmed/23424500
http://dx.doi.org/10.1107/S160053681205180X
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author Pradeep, Priyamvada
Khorasani, Sanaz
de Koning, Charles B.
Fernandes, Manuel A.
author_facet Pradeep, Priyamvada
Khorasani, Sanaz
de Koning, Charles B.
Fernandes, Manuel A.
author_sort Pradeep, Priyamvada
collection PubMed
description The title indole derivative, C(17)H(15)NO(3)S, crystallizes with two independent mol­ecules in the asymmetric unit. The benzene ring of the tosyl group is almost perpedicular to the indole ring in both mol­ecules, with inter­planar angles of 82.60 (5)° and 81.82 (6)°. The two mol­ecules are, as a consequence, able to form an almost centrosymmetric non-bonded dimer, in which the molecules are linked by pairs of C—H⋯π inter­actions. The crystal structure displays a three-dimensional network of C—H⋯O inter­actions. A π–π inter­action occurs between inversion-related indole rings with a centroid–centroid distance of 3.6774 (16) Å and an inter­planar angle of 1.53 (15)°. This inter­action leads to a stacking of mol­ecules along the a axis.
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spelling pubmed-35697542013-02-19 3-Methyl-1-tosyl-1H-indole-2-carbaldehyde Pradeep, Priyamvada Khorasani, Sanaz de Koning, Charles B. Fernandes, Manuel A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title indole derivative, C(17)H(15)NO(3)S, crystallizes with two independent mol­ecules in the asymmetric unit. The benzene ring of the tosyl group is almost perpedicular to the indole ring in both mol­ecules, with inter­planar angles of 82.60 (5)° and 81.82 (6)°. The two mol­ecules are, as a consequence, able to form an almost centrosymmetric non-bonded dimer, in which the molecules are linked by pairs of C—H⋯π inter­actions. The crystal structure displays a three-dimensional network of C—H⋯O inter­actions. A π–π inter­action occurs between inversion-related indole rings with a centroid–centroid distance of 3.6774 (16) Å and an inter­planar angle of 1.53 (15)°. This inter­action leads to a stacking of mol­ecules along the a axis. International Union of Crystallography 2013-01-12 /pmc/articles/PMC3569754/ /pubmed/23424500 http://dx.doi.org/10.1107/S160053681205180X Text en © Pradeep et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pradeep, Priyamvada
Khorasani, Sanaz
de Koning, Charles B.
Fernandes, Manuel A.
3-Methyl-1-tosyl-1H-indole-2-carbaldehyde
title 3-Methyl-1-tosyl-1H-indole-2-carbaldehyde
title_full 3-Methyl-1-tosyl-1H-indole-2-carbaldehyde
title_fullStr 3-Methyl-1-tosyl-1H-indole-2-carbaldehyde
title_full_unstemmed 3-Methyl-1-tosyl-1H-indole-2-carbaldehyde
title_short 3-Methyl-1-tosyl-1H-indole-2-carbaldehyde
title_sort 3-methyl-1-tosyl-1h-indole-2-carbaldehyde
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569754/
https://www.ncbi.nlm.nih.gov/pubmed/23424500
http://dx.doi.org/10.1107/S160053681205180X
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