Methyl 2,4-dihy­droxy-5-(2-methyl­propanamido)­benzoate

In the title compound, C(12)H(15)NO(5), the dihedral angle between the benzene ring and the C atoms of the terminal isopropyl group is 83.48 (16)°. Intra­molecular N—H⋯O and O—H⋯O hydrogen bonds generate S(5) and S(6) rings, respectively. In the crystal, mol­ecules are linked by O—H⋯O hydrogen bonds...

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Autores principales: Naz, Syeda Sohaila, Islam, Nazar Ul, Tahir, M. Nawaz, Shah, Muhammad Raza
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569756/
https://www.ncbi.nlm.nih.gov/pubmed/23424502
http://dx.doi.org/10.1107/S1600536813000457
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author Naz, Syeda Sohaila
Islam, Nazar Ul
Tahir, M. Nawaz
Shah, Muhammad Raza
author_facet Naz, Syeda Sohaila
Islam, Nazar Ul
Tahir, M. Nawaz
Shah, Muhammad Raza
author_sort Naz, Syeda Sohaila
collection PubMed
description In the title compound, C(12)H(15)NO(5), the dihedral angle between the benzene ring and the C atoms of the terminal isopropyl group is 83.48 (16)°. Intra­molecular N—H⋯O and O—H⋯O hydrogen bonds generate S(5) and S(6) rings, respectively. In the crystal, mol­ecules are linked by O—H⋯O hydrogen bonds, generating C(7) chains propagating in [001]. Weak aromatic π–π stacking [centroid–centroid separation = 3.604 (3) Å] is also observed.
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spelling pubmed-35697562013-02-19 Methyl 2,4-dihy­droxy-5-(2-methyl­propanamido)­benzoate Naz, Syeda Sohaila Islam, Nazar Ul Tahir, M. Nawaz Shah, Muhammad Raza Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(15)NO(5), the dihedral angle between the benzene ring and the C atoms of the terminal isopropyl group is 83.48 (16)°. Intra­molecular N—H⋯O and O—H⋯O hydrogen bonds generate S(5) and S(6) rings, respectively. In the crystal, mol­ecules are linked by O—H⋯O hydrogen bonds, generating C(7) chains propagating in [001]. Weak aromatic π–π stacking [centroid–centroid separation = 3.604 (3) Å] is also observed. International Union of Crystallography 2013-01-12 /pmc/articles/PMC3569756/ /pubmed/23424502 http://dx.doi.org/10.1107/S1600536813000457 Text en © Naz et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Naz, Syeda Sohaila
Islam, Nazar Ul
Tahir, M. Nawaz
Shah, Muhammad Raza
Methyl 2,4-dihy­droxy-5-(2-methyl­propanamido)­benzoate
title Methyl 2,4-dihy­droxy-5-(2-methyl­propanamido)­benzoate
title_full Methyl 2,4-dihy­droxy-5-(2-methyl­propanamido)­benzoate
title_fullStr Methyl 2,4-dihy­droxy-5-(2-methyl­propanamido)­benzoate
title_full_unstemmed Methyl 2,4-dihy­droxy-5-(2-methyl­propanamido)­benzoate
title_short Methyl 2,4-dihy­droxy-5-(2-methyl­propanamido)­benzoate
title_sort methyl 2,4-dihy­droxy-5-(2-methyl­propanamido)­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569756/
https://www.ncbi.nlm.nih.gov/pubmed/23424502
http://dx.doi.org/10.1107/S1600536813000457
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