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(S)-2,2′-Dihydroxy-N,N′-(6-hydroxyhexane-1,5-diyl)dibenzamide
In the title compound, C(20)H(24)N(2)O(5), the dihedral angle between the two roughly planar salicylamide fragments [r.m.s. deviations = 0.043 (2) and 0.149 (2) Å] is 25.50 (5)°. The molecular conformation is stabilized by intramolecular O—H⋯O hydrogen bonds involving phenol –OH groups and amide...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569758/ https://www.ncbi.nlm.nih.gov/pubmed/23424504 http://dx.doi.org/10.1107/S1600536813000354 |
Sumario: | In the title compound, C(20)H(24)N(2)O(5), the dihedral angle between the two roughly planar salicylamide fragments [r.m.s. deviations = 0.043 (2) and 0.149 (2) Å] is 25.50 (5)°. The molecular conformation is stabilized by intramolecular O—H⋯O hydrogen bonds involving phenol –OH groups and amide O atoms. Intermolecular hydroxymethyl–amide O—H⋯O and amine–hydroxymethyl N—H⋯O hydrogen bonds form infinite chains along the b axis. These chains are further interlinked by amine–amide N—H⋯O and phenol–phenol O—H⋯O interactions, thus giving layers parallel to (001). |
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