(S)-2,2′-Dihy­droxy-N,N′-(6-hy­droxy­hexane-1,5-di­yl)dibenzamide

In the title compound, C(20)H(24)N(2)O(5), the dihedral angle between the two roughly planar salicyl­amide fragments [r.m.s. deviations = 0.043 (2) and 0.149 (2) Å] is 25.50 (5)°. The mol­ecular conformation is stabilized by intra­molecular O—H⋯O hydrogen bonds involving phenol –OH groups and amide...

Descripción completa

Detalles Bibliográficos
Autores principales: Wilbrand, Sabine, Neis, Christian, Hegetschweiler, Kaspar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569758/
https://www.ncbi.nlm.nih.gov/pubmed/23424504
http://dx.doi.org/10.1107/S1600536813000354
_version_ 1782258955829903360
author Wilbrand, Sabine
Neis, Christian
Hegetschweiler, Kaspar
author_facet Wilbrand, Sabine
Neis, Christian
Hegetschweiler, Kaspar
author_sort Wilbrand, Sabine
collection PubMed
description In the title compound, C(20)H(24)N(2)O(5), the dihedral angle between the two roughly planar salicyl­amide fragments [r.m.s. deviations = 0.043 (2) and 0.149 (2) Å] is 25.50 (5)°. The mol­ecular conformation is stabilized by intra­molecular O—H⋯O hydrogen bonds involving phenol –OH groups and amide O atoms. Inter­molecular hy­droxy­meth­yl–amide O—H⋯O and amine–hy­droxy­methyl N—H⋯O hydrogen bonds form infinite chains along the b axis. These chains are further inter­linked by amine–amide N—H⋯O and phenol–phenol O—H⋯O inter­actions, thus giving layers parallel to (001).
format Online
Article
Text
id pubmed-3569758
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-35697582013-02-19 (S)-2,2′-Dihy­droxy-N,N′-(6-hy­droxy­hexane-1,5-di­yl)dibenzamide Wilbrand, Sabine Neis, Christian Hegetschweiler, Kaspar Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(24)N(2)O(5), the dihedral angle between the two roughly planar salicyl­amide fragments [r.m.s. deviations = 0.043 (2) and 0.149 (2) Å] is 25.50 (5)°. The mol­ecular conformation is stabilized by intra­molecular O—H⋯O hydrogen bonds involving phenol –OH groups and amide O atoms. Inter­molecular hy­droxy­meth­yl–amide O—H⋯O and amine–hy­droxy­methyl N—H⋯O hydrogen bonds form infinite chains along the b axis. These chains are further inter­linked by amine–amide N—H⋯O and phenol–phenol O—H⋯O inter­actions, thus giving layers parallel to (001). International Union of Crystallography 2013-01-12 /pmc/articles/PMC3569758/ /pubmed/23424504 http://dx.doi.org/10.1107/S1600536813000354 Text en © Wilbrand et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wilbrand, Sabine
Neis, Christian
Hegetschweiler, Kaspar
(S)-2,2′-Dihy­droxy-N,N′-(6-hy­droxy­hexane-1,5-di­yl)dibenzamide
title (S)-2,2′-Dihy­droxy-N,N′-(6-hy­droxy­hexane-1,5-di­yl)dibenzamide
title_full (S)-2,2′-Dihy­droxy-N,N′-(6-hy­droxy­hexane-1,5-di­yl)dibenzamide
title_fullStr (S)-2,2′-Dihy­droxy-N,N′-(6-hy­droxy­hexane-1,5-di­yl)dibenzamide
title_full_unstemmed (S)-2,2′-Dihy­droxy-N,N′-(6-hy­droxy­hexane-1,5-di­yl)dibenzamide
title_short (S)-2,2′-Dihy­droxy-N,N′-(6-hy­droxy­hexane-1,5-di­yl)dibenzamide
title_sort (s)-2,2′-dihy­droxy-n,n′-(6-hy­droxy­hexane-1,5-di­yl)dibenzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569758/
https://www.ncbi.nlm.nih.gov/pubmed/23424504
http://dx.doi.org/10.1107/S1600536813000354
work_keys_str_mv AT wilbrandsabine s22dihydroxynn6hydroxyhexane15diyldibenzamide
AT neischristian s22dihydroxynn6hydroxyhexane15diyldibenzamide
AT hegetschweilerkaspar s22dihydroxynn6hydroxyhexane15diyldibenzamide

Ejemplares similares