Dimethyl 2-[(acridin-9-yl)methyl­idene]malonate

In the title compound, C(19)H(15)NO(4), the acridine system is essentially planar (r.m.s. deviation = 0.015 Å). The crystal packing exhibits π–π inter­actions between pairs of centrosymmetric mol­ecules, one of them between the central heterocyclic rings and others between the outer benzene rings of...

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Detalles Bibliográficos
Autores principales: de Almeida, Sinara M. V., Pitta, Ivan R., de Lima, Maria do Carmo A., Mendonça Junior, Francisco J. B., de Simone, Carlos A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569759/
https://www.ncbi.nlm.nih.gov/pubmed/23424505
http://dx.doi.org/10.1107/S1600536813000500
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author de Almeida, Sinara M. V.
Pitta, Ivan R.
de Lima, Maria do Carmo A.
Mendonça Junior, Francisco J. B.
de Simone, Carlos A.
author_facet de Almeida, Sinara M. V.
Pitta, Ivan R.
de Lima, Maria do Carmo A.
Mendonça Junior, Francisco J. B.
de Simone, Carlos A.
author_sort de Almeida, Sinara M. V.
collection PubMed
description In the title compound, C(19)H(15)NO(4), the acridine system is essentially planar (r.m.s. deviation = 0.015 Å). The crystal packing exhibits π–π inter­actions between pairs of centrosymmetric mol­ecules, one of them between the central heterocyclic rings and others between the outer benzene rings of the acridine systems, with centroid–centroid distances of 3.692 (1) and 3.754 (1) Å, respectively. These pairs are further linked by additional π–π inter­actions along the a-axis direction through one of the two outer benzene ring of neighboring mol­ecules, with a centroid–centroid distance of 3.642 (2) Å.
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spelling pubmed-35697592013-02-19 Dimethyl 2-[(acridin-9-yl)methyl­idene]malonate de Almeida, Sinara M. V. Pitta, Ivan R. de Lima, Maria do Carmo A. Mendonça Junior, Francisco J. B. de Simone, Carlos A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(15)NO(4), the acridine system is essentially planar (r.m.s. deviation = 0.015 Å). The crystal packing exhibits π–π inter­actions between pairs of centrosymmetric mol­ecules, one of them between the central heterocyclic rings and others between the outer benzene rings of the acridine systems, with centroid–centroid distances of 3.692 (1) and 3.754 (1) Å, respectively. These pairs are further linked by additional π–π inter­actions along the a-axis direction through one of the two outer benzene ring of neighboring mol­ecules, with a centroid–centroid distance of 3.642 (2) Å. International Union of Crystallography 2013-01-12 /pmc/articles/PMC3569759/ /pubmed/23424505 http://dx.doi.org/10.1107/S1600536813000500 Text en © Almeida et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
de Almeida, Sinara M. V.
Pitta, Ivan R.
de Lima, Maria do Carmo A.
Mendonça Junior, Francisco J. B.
de Simone, Carlos A.
Dimethyl 2-[(acridin-9-yl)methyl­idene]malonate
title Dimethyl 2-[(acridin-9-yl)methyl­idene]malonate
title_full Dimethyl 2-[(acridin-9-yl)methyl­idene]malonate
title_fullStr Dimethyl 2-[(acridin-9-yl)methyl­idene]malonate
title_full_unstemmed Dimethyl 2-[(acridin-9-yl)methyl­idene]malonate
title_short Dimethyl 2-[(acridin-9-yl)methyl­idene]malonate
title_sort dimethyl 2-[(acridin-9-yl)methyl­idene]malonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569759/
https://www.ncbi.nlm.nih.gov/pubmed/23424505
http://dx.doi.org/10.1107/S1600536813000500
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