[(1R,3S)-2,2-Dichloro-3-(hy­droxy­meth­yl)cyclo­prop­yl]methanol

The title compound, C(5)H(8)Cl(2)O(2), represents a meso isomer crystallizing in a chiral space group with two mol­ecules per asymmetric unit. The mol­ecules form helical associates with a pitch of 6.31 Å along the a axis via O—H⋯O hydrogen bonds. The overall three-dimesional supra­molecular archite...

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Detalles Bibliográficos
Autor principal: Kailani, Mohammed H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569760/
https://www.ncbi.nlm.nih.gov/pubmed/23424506
http://dx.doi.org/10.1107/S1600536813000366
Descripción
Sumario:The title compound, C(5)H(8)Cl(2)O(2), represents a meso isomer crystallizing in a chiral space group with two mol­ecules per asymmetric unit. The mol­ecules form helical associates with a pitch of 6.31 Å along the a axis via O—H⋯O hydrogen bonds. The overall three-dimesional supra­molecular architecture is stabilized by C—Cl⋯O halogen bonding, with a Cl⋯O separation of 3.139 (3) Å and a C—Cl⋯O angle of 162.5 (2)°.

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