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[(1R,3S)-2,2-Dichloro-3-(hydroxymethyl)cyclopropyl]methanol
The title compound, C(5)H(8)Cl(2)O(2), represents a meso isomer crystallizing in a chiral space group with two molecules per asymmetric unit. The molecules form helical associates with a pitch of 6.31 Å along the a axis via O—H⋯O hydrogen bonds. The overall three-dimesional supramolecular archite...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2013
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569760/ https://www.ncbi.nlm.nih.gov/pubmed/23424506 http://dx.doi.org/10.1107/S1600536813000366 |
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author | Kailani, Mohammed H. |
author_facet | Kailani, Mohammed H. |
author_sort | Kailani, Mohammed H. |
collection | PubMed |
description | The title compound, C(5)H(8)Cl(2)O(2), represents a meso isomer crystallizing in a chiral space group with two molecules per asymmetric unit. The molecules form helical associates with a pitch of 6.31 Å along the a axis via O—H⋯O hydrogen bonds. The overall three-dimesional supramolecular architecture is stabilized by C—Cl⋯O halogen bonding, with a Cl⋯O separation of 3.139 (3) Å and a C—Cl⋯O angle of 162.5 (2)°. |
format | Online Article Text |
id | pubmed-3569760 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35697602013-02-19 [(1R,3S)-2,2-Dichloro-3-(hydroxymethyl)cyclopropyl]methanol Kailani, Mohammed H. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(5)H(8)Cl(2)O(2), represents a meso isomer crystallizing in a chiral space group with two molecules per asymmetric unit. The molecules form helical associates with a pitch of 6.31 Å along the a axis via O—H⋯O hydrogen bonds. The overall three-dimesional supramolecular architecture is stabilized by C—Cl⋯O halogen bonding, with a Cl⋯O separation of 3.139 (3) Å and a C—Cl⋯O angle of 162.5 (2)°. International Union of Crystallography 2013-01-12 /pmc/articles/PMC3569760/ /pubmed/23424506 http://dx.doi.org/10.1107/S1600536813000366 Text en © Mohammed H. Kailani 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kailani, Mohammed H. [(1R,3S)-2,2-Dichloro-3-(hydroxymethyl)cyclopropyl]methanol |
title | [(1R,3S)-2,2-Dichloro-3-(hydroxymethyl)cyclopropyl]methanol |
title_full | [(1R,3S)-2,2-Dichloro-3-(hydroxymethyl)cyclopropyl]methanol |
title_fullStr | [(1R,3S)-2,2-Dichloro-3-(hydroxymethyl)cyclopropyl]methanol |
title_full_unstemmed | [(1R,3S)-2,2-Dichloro-3-(hydroxymethyl)cyclopropyl]methanol |
title_short | [(1R,3S)-2,2-Dichloro-3-(hydroxymethyl)cyclopropyl]methanol |
title_sort | [(1r,3s)-2,2-dichloro-3-(hydroxymethyl)cyclopropyl]methanol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569760/ https://www.ncbi.nlm.nih.gov/pubmed/23424506 http://dx.doi.org/10.1107/S1600536813000366 |
work_keys_str_mv | AT kailanimohammedh 1r3s22dichloro3hydroxymethylcyclopropylmethanol |